Poly[diaqua[μ4-4-(isonicotinamido)phthalato]nickel(II)] displaying an sra topology.

IF 0.8 4区化学

Acta crystallographica. Section C, Crystal structure communications Pub Date : 2013-10-01 Epub Date: 2013-09-06 DOI:10.1107/S0108270113023846

Man-Sheng Chen, Jin-Sheng Xu, Yi-Fang Deng, Chun-Hua Zhang

引用次数: 0

Abstract

In the title compound, [Ni(C14H8N2O5)(H2O)2]n, the Ni(II) cation is six-coordinate with a slightly distorted octahedral coordination geometry and the 4-(isonicotinamido)phthalate ligand links the Ni(II) centres into a three-dimensional structure with sra topology. The structure is also stabilized by N-H···O hydrogen bonding between the uncoordinated amide groups of the ligand and extensive O-H···O hydrogen bonding between the two coordinated water molecules. The magnetic and thermal stability properties of the title compound are also discussed.

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显示sra拓扑结构的聚[diaqua[μ4-4-（异烟酰胺基）邻苯二甲酸]镍（II）]。

在标题化合物[Ni(C14H8N2O5)(H2O)2]n中，Ni(II)阳离子是六坐标的，具有轻微扭曲的八面体配位几何，4-(异烟酰胺)邻苯二甲酸酯配体将Ni(II)中心连接成具有sra拓扑结构的三维结构。配体的非配位酰胺基团之间的N-H··O氢键和两个配位水分子之间广泛的O- h··O氢键也稳定了该结构。讨论了该化合物的磁性和热稳定性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Acta crystallographica. Section C, Crystal structure communications 化学-晶体学

自引率

12.50%

发文量

审稿时长

1 months

期刊介绍： Acta Crystallographica Section C: Structural Chemistry is continuing its transition to a journal that publishes exciting science with structural content, in particular, important results relating to the chemical sciences. Section C is the journal of choice for the rapid publication of articles that highlight interesting research facilitated by the determination, calculation or analysis of structures of any type, other than macromolecular structures. Articles that emphasize the science and the outcomes that were enabled by the study are particularly welcomed. Authors are encouraged to include mainstream science in their papers, thereby producing manuscripts that are substantial scientific well-rounded contributions that appeal to a broad community of readers and increase the profile of the authors.