Langmuir-blodgett films of supported polyester dendrimers.

ISRN Organic Chemistry Pub Date : 2012-10-16 eCollection Date: 2012-01-01 DOI:10.5402/2012/906839
Rocío Redón, M Pilar Carreón-Castro, F J Mendoza-Martínez
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Abstract

Amphiphiles with a dendritic structure are attractive materials as they combine the features of dendrimers with the self-assembling properties and interfacial behavior of water-air affinities. We have synthesized three generations of polyester dendrimers and studied their interfacial properties on the Langmuir films. The behavior obtained was, as a rule, the lowest generation dendrimers behaving like traditional amphiphiles and the larger molecules presenting complicated isotherms. The Langmuir films of these compounds have been characterized by their surface pressure versus molecular area (π/A) and Brewster angle microscopy (BAM) observations.

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支撑聚酯树枝状聚合物的 Langmuir-blodgett 薄膜。
具有树枝状结构的两性化合物是一种极具吸引力的材料,因为它们结合了树枝状聚合物的特征、自组装特性和水气亲和性的界面行为。我们合成了三代聚酯树枝状聚合物,并研究了它们在朗缪尔薄膜上的界面特性。研究结果表明,最低代树枝状聚合物通常表现为传统的两性化合物,而较大的分子则表现为复杂的等温线。这些化合物的朗缪尔薄膜通过表面压力与分子面积的关系(π/A)和布鲁斯特角显微镜(BAM)进行了表征。
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