Insight into the anti-corrosion performance of synthesized novel nano polymeric material of SiO2 for the protection of J55 steel in 3.5 wt% NaCl solution saturated with carbon dioxide

IF 4.9 2区 工程技术 Q2 ENERGY & FUELS
Wenlong Song , Xia Dayu , Liu Mingxing , K.R. Ansari , Ambrish Singh
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引用次数: 6

Abstract

The oil and gas industry faces a great challenge and loss due to corrosion in the sweet aggressive medium. To overcome this effect addition of corrosion inhibitors, especially eco-friendly ones, are the prime additive. The description in this paper includes the synthesis of nano-sized novel polymeric composite material of SiO2, i.e., n-SiO2/P (ANA), and its application as a sweet corrosion inhibitor (3.5 wt% NaCl saturated with CO2) for J55 steel. The characterization of synthesized n-SiO2/P (ANA) was done via spectroscopic techniques. The chemical and electrochemical methods were used to evaluate the inhibitive performance. The surface texture of both protected and corroded samples was analyzed via scanning electron microscopy (SEM), Energy-dispersive X-ray spectroscopy (EDX), and atomic force microscopy (AFM). The results of EIS and PDP reveal the increase in Rct values with the rising amount of n-SiO2/P (ANA) and the anodic nature of n-SiO2/P (ANA) inhibiting action. The maximum inhibitive performance result is 92% at 400 mg/L. The Langmuir plot supports the best fitting experimental data. The surface study supports the n-SiO2/P (ANA) covering onto J55 steel.

Abstract Image

研究合成的新型纳米SiO2聚合材料在含二氧化碳的3.5 wt% NaCl溶液中对J55钢的防腐性能
由于含硫侵蚀介质的腐蚀,油气行业面临着巨大的挑战和损失。为了克服这一影响,添加缓蚀剂,特别是环保型缓蚀剂是首选添加剂。本文介绍了新型纳米SiO2聚合复合材料n-SiO2/P (ANA)的合成及其作为J55钢的缓蚀剂(3.5 wt% NaCl饱和CO2)的应用。利用光谱技术对合成的n-SiO2/P (ANA)进行了表征。采用化学和电化学方法对其抑菌性能进行了评价。通过扫描电子显微镜(SEM)、能量色散x射线能谱(EDX)和原子力显微镜(AFM)分析了保护和腐蚀样品的表面织构。EIS和PDP结果显示,Rct值随n-SiO2/P (ANA)用量的增加而增加,且n-SiO2/P (ANA)的抑制作用为阳极性质。当浓度为400 mg/L时,抑制效果达到92%。Langmuir图支持最佳拟合实验数据。表面研究支持n-SiO2/P (ANA)覆盖在J55钢上。
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来源期刊
Journal of Natural Gas Science and Engineering
Journal of Natural Gas Science and Engineering ENERGY & FUELS-ENGINEERING, CHEMICAL
CiteScore
8.90
自引率
0.00%
发文量
388
审稿时长
3.6 months
期刊介绍: The objective of the Journal of Natural Gas Science & Engineering is to bridge the gap between the engineering and the science of natural gas by publishing explicitly written articles intelligible to scientists and engineers working in any field of natural gas science and engineering from the reservoir to the market. An attempt is made in all issues to balance the subject matter and to appeal to a broad readership. The Journal of Natural Gas Science & Engineering covers the fields of natural gas exploration, production, processing and transmission in its broadest possible sense. Topics include: origin and accumulation of natural gas; natural gas geochemistry; gas-reservoir engineering; well logging, testing and evaluation; mathematical modelling; enhanced gas recovery; thermodynamics and phase behaviour, gas-reservoir modelling and simulation; natural gas production engineering; primary and enhanced production from unconventional gas resources, subsurface issues related to coalbed methane, tight gas, shale gas, and hydrate production, formation evaluation; exploration methods, multiphase flow and flow assurance issues, novel processing (e.g., subsea) techniques, raw gas transmission methods, gas processing/LNG technologies, sales gas transmission and storage. The Journal of Natural Gas Science & Engineering will also focus on economical, environmental, management and safety issues related to natural gas production, processing and transportation.
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