Synthesis and physical properties of estolide ester using saturated Fatty Acid and ricinoleic Acid.

Jumat Salimon, Neeranjini Nallathamby, Nadia Salih, Bashar Mudhaffar Abdullah
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引用次数: 14

Abstract

A study was conveyed to produce estolide ester using ricinoleic acid as the backbone. The ricinoleic acid reacted with saturated fatty acid from C8-C18. These reactions were conducted under vacuum at 60°C for 24 h without solvent. The reaction used acid catalyst, sulphuric acid. The new saturate ricinoleic estolide esters show superior low-temperature properties (-52 ± 0.08°C) and high flash point (>300°C). The yield of the neat estolide esters ranged from 52% to 96%. The viscosity range was 51 ± 0.08 to 86 ± 0.01 cp. These new saturated estolide esters were also compared with saturated branched estolide esters.

Abstract Image

饱和脂肪酸和蓖麻油酸酯的合成及其物理性质。
介绍了以蓖麻油酸为骨架制备蓖麻油酸酯的研究。蓖麻油酸与C8-C18的饱和脂肪酸反应。这些反应在真空条件下60°C下无溶剂进行24 h。该反应采用酸性催化剂硫酸。新型饱和蓖麻油酸酯具有优良的低温性能(-52±0.08℃)和高闪点(>300℃)。所得纯酯的收率为52% ~ 96%。黏度范围为51±0.08 ~ 86±0.01 cp。并与饱和支链甾醇酯进行了比较。
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