An Investigation on Calcium (II) Oxalate as Solubility and Universal Standard

Marco Antonilli, Emilio Bottari, Maria Rosa Festa, Lorella Gentile
{"title":"An Investigation on Calcium (II) Oxalate as Solubility and Universal Standard","authors":"Marco Antonilli,&nbsp;Emilio Bottari,&nbsp;Maria Rosa Festa,&nbsp;Lorella Gentile","doi":"10.1002/adic.200790092","DOIUrl":null,"url":null,"abstract":"<p>The investigation on calcium (II) oxalate is carried out in order to study its solubility in different ionic media. In the same conditions the protonation constants of oxalate and the stability of complex species have been determined. As the stoichiometric composition of the solid calcium (II) oxalate prepared for the investigation was accurately checked, the salt CaC<sub>2</sub>O<sub>4</sub> · H<sub>2</sub>O is proposed as universal (chelometry, redox, acidimetry) standard. Results of titrations support this possibility.</p>","PeriodicalId":8193,"journal":{"name":"Annali di chimica","volume":"97 10","pages":"1085-1096"},"PeriodicalIF":0.0000,"publicationDate":"2007-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/adic.200790092","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Annali di chimica","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/adic.200790092","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2

Abstract

The investigation on calcium (II) oxalate is carried out in order to study its solubility in different ionic media. In the same conditions the protonation constants of oxalate and the stability of complex species have been determined. As the stoichiometric composition of the solid calcium (II) oxalate prepared for the investigation was accurately checked, the salt CaC2O4 · H2O is proposed as universal (chelometry, redox, acidimetry) standard. Results of titrations support this possibility.

草酸钙作为溶解度和通用标准的研究
对草酸钙(II)在不同离子介质中的溶解度进行了研究。在相同条件下测定了草酸的质子化常数和络合物的稳定性。对制备的固体草酸钙(II)的化学计量成分进行了准确的测定,提出以CaC2O4·H2O盐作为通用(螯合、氧化还原、酸化)标准盐。滴定结果支持这种可能性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信