Scaled structures in late stages of microphase separation of binary paraffin mixtures

Zhu, White, Epperson
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Abstract

Since the dynamic properties in paraffin mixtures are different from those in alloys and polymer blends, paraffin mixtures are believed to be another class of substances establishing the "universality" of the dynamical scaling behavior of phase separation. In this paper, the scaled structures of microphase separation in paraffin mixtures are described using a scaling function based on a two-phase model with kinetics based on the Cahn-Hilliard equation. It has been demonstrated that at the late stages of the microphase separation the scaling behavior in the paraffin mixtures agrees well with the universal features predicted by the scaling function. The scaled structures of microphase separation in paraffin mixtures can be directly calculated from the volume fraction of the minority phase without any adjustable parameter.

二元石蜡混合物微相分离后期的尺度结构
由于石蜡混合物的动力学性质不同于合金和聚合物混合物,因此石蜡混合物被认为是另一类物质,建立了相分离动力学结垢行为的“通用性”。本文采用基于Cahn-Hilliard方程动力学的两相模型的标度函数描述了石蜡混合物中微相分离的标度结构。结果表明,在微相分离后期,石蜡混合物中的结垢行为与用结垢函数预测的普遍特征吻合得很好。由少量相的体积分数可以直接计算出石蜡混合物中微相分离的尺度结构,无需任何可调参数。
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