Observation of Li+ jumps in solid inorganic electrolytes over a broad dynamical range: A case study of the lithium phosphidosilicates Li8SiP4 and Li14SiP6

IF 2.624
Björn Wankmiller , Michael Ryan Hansen
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引用次数: 2

Abstract

7Li NMR spectroscopy is known to be very sensitive to translational motion in solids and therefore highly suited for investigating temperature-dependent Li+ dynamics. A number of different NMR methods are available for choosing the dynamical range of the observed Li+ jump frequencies present in inorganic solid-state electrolytes. This includes 7Li spin-alignment echo NMR spectroscopy, static 7Li lineshape analysis, and 7Li spin-lattice relaxometry that can be used to detect Li+ jumps in the Hz, kHz, and MHz range, respectively. We introduce and discuss these NMR techniques with respect to their theoretical description and practical application to investigate the Li+ dynamics at different time scales for the two solid-state electrolytes Li8SiP4 and Li14SiP6. The data evaluation for all methods is discussed in detail, focusing on the determination of Li+ jump frequencies and activation energies for the investigated self-diffusion processes in a given structure.

Abstract Image

固体无机电解质中Li+跃迁的宽动态范围观察:以磷酸硅酸锂Li8SiP4和Li14SiP6为例
众所周知,Li核磁共振光谱对固体中的平移运动非常敏感,因此非常适合研究温度依赖的Li+动力学。许多不同的核磁共振方法可用于选择在无机固态电解质中观察到的Li+跳变频率的动态范围。这包括7Li自旋对准回波核磁共振光谱,静态7Li线形分析和7Li自旋晶格弛豫测量,可分别用于检测Hz, kHz和MHz范围内的Li+跳跃。我们介绍并讨论了这些核磁共振技术的理论描述和实际应用,以研究两种固态电解质Li8SiP4和Li14SiP6在不同时间尺度上的Li+动力学。详细讨论了所有方法的数据评估,重点讨论了给定结构中所研究的自扩散过程的Li+跳变频率和活化能的确定。
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CiteScore
1.90
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