Comparative Study of Techniques Used to Determine Asphaltene Stability

IF 1.1 4区 工程技术 Q3 CHEMISTRY, ORGANIC
Ali A. Ali
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Abstract

The condition of asphaltene deposition is poorly known, creating it one of the heaviest challenging flow assurance issues in oil production. An important stage of this problem is asphaltene stability, which indicates whether the asphaltene can be precipitated from a petroleum sample. This study investigated the efficiency of many forecasting models used to evaluate asphaltene stability in the petroleum depending only on SARA (Saturate, Aromatics, Resins and Asphaltene) fractions. To identify the precision of eight models of asphaltene stability, 298 crude oil samples from various worldwide sources were examined. By exhibiting obvious distinctions in sample sorting between the models, the findings showed the impact of methodological assumptions and fundamental factors. The factors of confusion matrix were utilized to statistically evaluate each prediction model’s performance. The Colloidal Stability Index (CSI) was selected as the most reliable technique as it is showed the highest overall accuracy among all the examined models. Additionally, CSI was conducted to examine the stability condition of asphaltene in Iraqi petroleum samples, and the predicted results were matched the experimental findings because they were all prone to asphaltene precipitation (unstable samples).

沥青质稳定性测定技术的比较研究
沥青质沉积的条件鲜为人知,使其成为石油生产中最具挑战性的流动保证问题之一。这个问题的一个重要阶段是沥青质稳定性,它表明沥青质能否从石油样品中析出。本研究考察了许多预测模型的有效性,这些模型仅依赖于SARA(饱和组分、芳烃组分、树脂组分和沥青质组分)馏分来评估石油中沥青质的稳定性。为了确定8种沥青质稳定性模型的精度,对来自世界各地的298种原油样品进行了检查。通过对模型样本排序的明显差异,研究结果表明了方法假设和基本因素的影响。利用混淆矩阵因子对各预测模型的性能进行统计评价。胶体稳定指数(CSI)被选为最可靠的技术,因为它在所有被检查的模型中显示出最高的总体准确性。此外,对伊拉克石油样品中沥青质的稳定性进行了CSI检测,由于伊拉克石油样品都容易发生沥青质的沉淀(不稳定样品),预测结果与实验结果吻合。
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来源期刊
Petroleum Chemistry
Petroleum Chemistry 工程技术-工程:化工
CiteScore
2.50
自引率
21.40%
发文量
102
审稿时长
6-12 weeks
期刊介绍: Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas. Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.
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