Conceptual Interpretation and Practical Teaching Design of Ideal Work and Lost Work: Comments on Chemical Engineering Thermodynamics Textbooks

IF 3 3区 教育学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Journal of Chemical Education Pub Date : 2026-10-13 Epub Date: 2026-09-17 DOI:10.1021/acs.jchemed.6c01256
Rui Yang, Xin Yuan
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引用次数: 0

Abstract

Ideal work and lost work are key contents connecting the second law of thermodynamics and engineering practice, and they pose major teaching challenges in chemical engineering thermodynamics courses. Mainstream textbooks widely use a two-step model including adiabatic reversible expansion and Carnot engine cooling to interpret ideal work, yet they ignore the intermediate reversible heat engine in description. This omission easily causes students to form misunderstandings of core concepts, symbols and the physical implication of the T0ΔS term. Combined with long-term frontline teaching experience and analysis of student learning difficulties, this paper reinterprets the essence of ideal work from the perspective of exergy difference, supplements the infinitesimal Carnot cycle model omitted in textbooks, and clarifies that T0ΔS is an exergy accounting correction term instead of actual heat flow. This paper summarizes three typical inappropriate expressions in existing textbooks and explains the nature of lost work as energy quality degradation caused by entropy generation. A practical four-step classroom teaching procedure, namely intuition establishment, physical deconstruction, formula derivation and engineering sublimation, is put forward according to students’ cognitive characteristics. Quantitative evaluation data from three consecutive semesters of teaching practice confirm that this teaching design effectively helps students break through learning obstacles and improves teaching effectiveness. The contents of this paper can serve as a practical reference for textbook revision and daily classroom teaching for thermodynamics educators.

理想功与失功的概念阐释与实践教学设计——对化工热力学教材的评析
理想功和失功是热力学第二定律与工程实践相联系的重要内容,是化工热力学课程教学的主要难点。主流教科书广泛使用绝热可逆膨胀和卡诺热机冷却两步模型来解释理想功,但在描述中忽略了中间可逆热机。这种遗漏容易导致学生对T0ΔS术语的核心概念、符号和物理含义产生误解。本文结合长期的一线教学经验和对学生学习困难的分析,从火用差的角度重新诠释了理想功的本质,补充了教科书中遗漏的无穷小卡诺循环模型,阐明了T0ΔS是一个代替实际热流的火用核算修正终端。本文总结了现有教科书中三种典型的不恰当表述,并解释了功损的本质是熵产生引起的能量质量退化。根据学生的认知特点,提出了直观建立、物理解构、公式推导和工程升华四步实践性课堂教学流程。连续三个学期的教学实践量化评价数据证实,这种教学设计有效地帮助学生突破学习障碍,提高教学效果。本文的研究内容可作为教材修订和日常课堂教学的实用参考。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Journal of Chemical Education
Journal of Chemical Education 化学-化学综合
CiteScore
5.60
自引率
50.00%
发文量
465
审稿时长
6.5 months
期刊介绍: The Journal of Chemical Education is the official journal of the Division of Chemical Education of the American Chemical Society, co-published with the American Chemical Society Publications Division. Launched in 1924, the Journal of Chemical Education is the world’s premier chemical education journal. The Journal publishes peer-reviewed articles and related information as a resource to those in the field of chemical education and to those institutions that serve them. JCE typically addresses chemical content, activities, laboratory experiments, instructional methods, and pedagogies. The Journal serves as a means of communication among people across the world who are interested in the teaching and learning of chemistry. This includes instructors of chemistry from middle school through graduate school, professional staff who support these teaching activities, as well as some scientists in commerce, industry, and government.
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