A New Determination of the Standard Enthalpy of Formation of the Lead Ion in Aqueous Solution

IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL
S. N. Soloviev, N. N. Barbotina, T. N. Ponamareva
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引用次数: 0

Abstract

The standard enthalpy of formation of the Pb2+ ion in aqueous solution was refined by measuring the enthalpy of solution of Pb(NO3)2(cr) in water and the enthalpies of interaction of Pb(NO3)2(cr) with an excess of aqueous potassium iodide and of Zn(cr, dust) with an excess of lead nitrate solution. The standard enthalpy of formation of the lead ion was determined by two independent methods.

水溶液中铅离子标准生成焓的新测定方法
通过测定Pb(NO3)2(cr)在水中的溶液焓、Pb(NO3)2(cr)与过量碘化钾水溶液和Zn(cr,粉尘)与过量硝酸铅溶液的相互作用焓,确定了Pb2+离子在水溶液中的标准生成焓。用两种独立的方法测定了铅离子的标准生成焓。
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来源期刊
CiteScore
1.20
自引率
14.30%
发文量
376
审稿时长
5.1 months
期刊介绍: Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.
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