Effect of Ni, Co, and W on the Reaction Sintering of cBN Composites

IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY
D. A. Stratiichuk, N. M. Belyavina, V. Z. Turkevich, S. P. Starik, Ya. M. Romanenko
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引用次数: 0

Abstract

The chemical interactions between components and high-pressure high-temperature (HPHT) reaction sintering processes (p = 7.7 GPa, T = 2200°C) were studied for superhard composites of groups BH and BL in the cBN–Me and cBN–TiCN–Me systems (where Me = Ni, Co, W with a content of 30 vol %). It was established that, during sintering for 60 s, there is no chemical interaction between the cBN–Me charge components, while the formation of a small amount (1–3 vol %) of additional phases (Ni3B or Co3B, W2B, and W2C) is observed for the cBN–TiCN–Me composites. For all the systems, the resulting metal ceramic has zero porosity and has a monolithic, homogeneous microstructure, in which the original morphology of cBN grains is preserved. The Young’s modulus ranges from 370 to 427 GPa, and the Vickers hardness is 18–25 GPa.

Ni、Co和W对cBN复合材料反应烧结的影响
研究了cBN-Me和cBN-TiCN-Me体系(其中Me = Ni, Co, W,含量为30 vol %)中BH和BL族超硬复合材料组分之间的化学相互作用和高压高温(HPHT)反应烧结工艺(p = 7.7 GPa, T = 2200℃)。结果表明,cBN-TiCN-Me复合材料在烧结60 s时,cBN-Me电荷组分之间没有化学相互作用,而cBN-TiCN-Me复合材料中形成了少量(1-3 vol %)的附加相(Ni3B或Co3B、W2B和W2C)。对于所有的体系,所得到的金属陶瓷具有零孔隙率,具有整体,均匀的微观结构,其中cBN晶粒的原始形态被保留。杨氏模量为370 ~ 427 GPa,维氏硬度为18 ~ 25 GPa。
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来源期刊
Journal of Superhard Materials
Journal of Superhard Materials MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
1.80
自引率
66.70%
发文量
26
审稿时长
2 months
期刊介绍: Journal of Superhard Materials presents up-to-date results of basic and applied research on production, properties, and applications of superhard materials and related tools. It publishes the results of fundamental research on physicochemical processes of forming and growth of single-crystal, polycrystalline, and dispersed materials, diamond and diamond-like films; developments of methods for spontaneous and controlled synthesis of superhard materials and methods for static, explosive and epitaxial synthesis. The focus of the journal is large single crystals of synthetic diamonds; elite grinding powders and micron powders of synthetic diamonds and cubic boron nitride; polycrystalline and composite superhard materials based on diamond and cubic boron nitride; diamond and carbide tools for highly efficient metal-working, boring, stone-working, coal mining and geological exploration; articles of ceramic; polishing pastes for high-precision optics; precision lathes for diamond turning; technologies of precise machining of metals, glass, and ceramics. The journal covers all fundamental and technological aspects of synthesis, characterization, properties, devices and applications of these materials. The journal welcomes manuscripts from all countries in the English language.
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