Melting of B12As2 Boron Subarsenide under Pressure

IF 1.2 4区材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY

Journal of Superhard Materials Pub Date : 2026-09-09 DOI:10.3103/S1063457626040076

V. L. Solozhenko

引用次数: 0

Abstract

Melting of rhombohedral boron subarsenide, B₁₂As₂, has been studied at pressures up to 8 GPa using quenching. It was found that above 2.5 GPa B₁₂As₂ melts congruently, and the melting curve has a positive slope (30 ± 6 K/GPa), indicating a lower density of the melt as compared to the solid phase. The melting point of B₁₂As₂ at ambient pressure has been estimated to be 2110(40) K.

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压力下B12As2亚砷化硼的熔化

在高达8gpa的压力下，用淬火方法研究了菱面体亚砷化硼B12As2的熔化。结果表明，在2.5 GPa以上，B12As2熔体均匀熔化，熔化曲线斜率为正（30±6 K/GPa），熔体密度低于固相。B12As2在环境压力下的熔点估计为2110(40)K。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Superhard Materials MATERIALS SCIENCE, MULTIDISCIPLINARY-

CiteScore

1.80

自引率

66.70%

发文量

审稿时长

2 months

期刊介绍： Journal of Superhard Materials presents up-to-date results of basic and applied research on production, properties, and applications of superhard materials and related tools. It publishes the results of fundamental research on physicochemical processes of forming and growth of single-crystal, polycrystalline, and dispersed materials, diamond and diamond-like films; developments of methods for spontaneous and controlled synthesis of superhard materials and methods for static, explosive and epitaxial synthesis. The focus of the journal is large single crystals of synthetic diamonds; elite grinding powders and micron powders of synthetic diamonds and cubic boron nitride; polycrystalline and composite superhard materials based on diamond and cubic boron nitride; diamond and carbide tools for highly efficient metal-working, boring, stone-working, coal mining and geological exploration; articles of ceramic; polishing pastes for high-precision optics; precision lathes for diamond turning; technologies of precise machining of metals, glass, and ceramics. The journal covers all fundamental and technological aspects of synthesis, characterization, properties, devices and applications of these materials. The journal welcomes manuscripts from all countries in the English language.