Growth, Structure, and Nonlinear Optical Performance of 2A5NPCC Single Crystals

IF 1.4 4区 化学 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL
S. Hawech, Y. Moussaoui, I. Ledoux-Rak, N. Ennaceur
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引用次数: 0

Abstract

This study reinvestigates the potential of 2-amino-5-nitropyridinium cadmium chloride as a candidate material for nonlinear optical applications. The crystal and its molecular structure were reinvestigated using single crystal X-ray diffraction. The Ultraviolet spectroscopy were recorded, and the compositional ratio of the sample was examined through energy-dispersive X-ray analysis. A comprehensive analysis of the compound’s thermal stability was also conducted. Results show that the crystal belongs to the monoclinic system with a centrosymmetric group C2/C. Employing the Kurtz and Perry technique, the nonlinear optical behavior of the compound was found to slightly surpass that of potassium dihydrogen phosphate by a factor of 0.98. This enhancement in nonlinear optical response positions the compound as an intriguing candidate as a frequency-doubling material.

2A5NPCC单晶的生长、结构和非线性光学性能
本研究重新探讨了2-氨基-5-硝基吡啶氯化镉作为非线性光学应用的候选材料的潜力。利用单晶x射线衍射对晶体及其分子结构进行了重新研究。记录了样品的紫外光谱,并通过能量色散x射线分析检测了样品的组成比。对该化合物的热稳定性进行了综合分析。结果表明,该晶体属于单斜晶系,具有中心对称基团C2/C。采用Kurtz和Perry技术,发现该化合物的非线性光学行为略高于磷酸二氢钾的0.98倍。这种非线性光学响应的增强使该化合物成为一种有趣的倍频材料。
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来源期刊
Russian Journal of Physical Chemistry B
Russian Journal of Physical Chemistry B 化学-物理:原子、分子和化学物理
CiteScore
2.20
自引率
71.40%
发文量
106
审稿时长
4-8 weeks
期刊介绍: Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.
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