Graphical Thermodynamics and the Works of J. Willard Gibbs

IF 2 4区材料科学 Q4 CHEMISTRY, PHYSICAL

Journal of Phase Equilibria and Diffusion Pub Date : 2026-06-03 DOI:10.1007/s11669-026-01251-5

David E. Laughlin

引用次数: 0

Abstract

In this paper aspects of the first two papers written by Gibbs on the topic of thermodynamics are discussed. These early papers set the stage for Gibbs’ major work on thermodynamics. His use of graphical methods and geometry are reviewed and display the reasoning behind his mathematical construction of thermodynamics. This paper ends with later extensions of his work to interesting graphical plots as well as an example taken from his later work on Statistical Mechanics.

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图解热力学和J.威拉德·吉布斯的著作

本文讨论了吉布斯前两篇关于热力学的论文的各个方面。这些早期的论文为吉布斯在热力学方面的主要工作奠定了基础。回顾了他对图形方法和几何的使用，并展示了他对热力学的数学构造背后的推理。这篇论文以他后来的工作扩展到有趣的图形图以及他后来在统计力学方面的工作中的一个例子作为结束。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Phase Equilibria and Diffusion 工程技术-材料科学：综合

CiteScore

2.50

自引率

7.10%

发文量

审稿时长

1 months

期刊介绍： The most trusted journal for phase equilibria and thermodynamic research, ASM International''s Journal of Phase Equilibria and Diffusion features critical phase diagram evaluations on scientifically and industrially important alloy systems, authored by international experts. The Journal of Phase Equilibria and Diffusion is critically reviewed and contains basic and applied research results, a survey of current literature and other pertinent articles. The journal covers the significance of diagrams as well as new research techniques, equipment, data evaluation, nomenclature, presentation and other aspects of phase diagram preparation and use. Content includes information on phenomena such as kinetic control of equilibrium, coherency effects, impurity effects, and thermodynamic and crystallographic characteristics. The journal updates systems previously published in the Bulletin of Alloy Phase Diagrams as new data are discovered.