A Digital Model for the Reactor of Laser Non-Oxidative Methane Conversion into Hydrocarbons

IF 0.9 Q4 ENGINEERING, CHEMICAL
V. N. Snytnikov, E. E. Peskova
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引用次数: 0

Abstract

To study the non-oxidative conversion of natural gas into valuable hydrocarbons and hydrogen, a digital model was developed for the reactor, in which laser radiation acts on a two-phase reaction medium consisting of a gas with suspended solid catalytic nanoparticles. The countercurrent flows of this gas-dust medium in the axially symmetric reactor tube absorb radiation in the area of their collision. Heat exchange with the wall along the length of a reactor with laser radiation during endothermic methane conversion was investigated. Laser radiation introduced into the medium locally increases its temperature at the outlet of resulting products from the reactor and shifts their composition towards aromatic compounds. The wall temperature of 1173 K and radiation provided the conversion of methane to hydrocarbons and hydrogen at a level of 65%. The combination of traditional and laser methods of energy transfer to the reaction medium is shown to be promising to control the selectivity of non-oxidative methane conversion.

激光非氧化甲烷转化为烃类反应器的数字模型
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来源期刊
Catalysis in Industry
Catalysis in Industry ENGINEERING, CHEMICAL-
CiteScore
1.30
自引率
14.30%
发文量
21
期刊介绍: The journal covers the following topical areas: Analysis of specific industrial catalytic processes: Production and use of catalysts in branches of industry: chemical, petrochemical, oil-refining, pharmaceutical, organic synthesis, fuel-energetic industries, environment protection, biocatalysis; technology of industrial catalytic processes (generalization of practical experience, improvements, and modernization); technology of catalysts production, raw materials and equipment; control of catalysts quality; starting, reduction, passivation, discharge, storage of catalysts; catalytic reactors.Theoretical foundations of industrial catalysis and technologies: Research, studies, and concepts : search for and development of new catalysts and new types of supports, formation of active components, and mechanochemistry in catalysis; comprehensive studies of work-out catalysts and analysis of deactivation mechanisms; studies of the catalytic process at different scale levels (laboratory, pilot plant, industrial); kinetics of industrial and newly developed catalytic processes and development of kinetic models; nonlinear dynamics and nonlinear phenomena in catalysis: multiplicity of stationary states, stepwise changes in regimes, etc. Advances in catalysis: Catalysis and gas chemistry; catalysis and new energy technologies; biocatalysis; nanocatalysis; catalysis and new construction materials.History of the development of industrial catalysis.
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