Liquid-Phase Hydrogenation of Norbornene Compounds. Stereochemistry, Kinetics, and Mechanism

IF 0.9 Q4 ENGINEERING, CHEMICAL

Catalysis in Industry Pub Date : 2026-08-17 DOI:10.1134/S2070050426700200

V. V. Zamalyutin, V. R. Flid, R. S. Shamsiev, A. I. Nichugovskii, E. V. Okuneva

引用次数: 0

Abstract

In this review, we summarize and systematize our own data on the key regularities in the liquid-phase hydrogenation of carbocyclic alkenes and dienes of norbornene series using the examples of norbornadiene, dicyclopentadiene, and 5-vinyl-2-norbornene over heterogeneous palladium catalysts. The hydrogenation conditions that ensure the preservation of the norbornane framework, as well as the most probable mechanisms of its occurrence, are considered. Based on kinetic and quantum chemical studies, the reactivity during hydrogenation of multiple bonds of various types was assessed, taking into account their adsorption characteristics.

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来源期刊

Catalysis in Industry ENGINEERING, CHEMICAL-

CiteScore

1.30

自引率

14.30%

发文量

期刊介绍： The journal covers the following topical areas: Analysis of specific industrial catalytic processes: Production and use of catalysts in branches of industry: chemical, petrochemical, oil-refining, pharmaceutical, organic synthesis, fuel-energetic industries, environment protection, biocatalysis; technology of industrial catalytic processes (generalization of practical experience, improvements, and modernization); technology of catalysts production, raw materials and equipment; control of catalysts quality; starting, reduction, passivation, discharge, storage of catalysts; catalytic reactors.Theoretical foundations of industrial catalysis and technologies: Research, studies, and concepts : search for and development of new catalysts and new types of supports, formation of active components, and mechanochemistry in catalysis; comprehensive studies of work-out catalysts and analysis of deactivation mechanisms; studies of the catalytic process at different scale levels (laboratory, pilot plant, industrial); kinetics of industrial and newly developed catalytic processes and development of kinetic models; nonlinear dynamics and nonlinear phenomena in catalysis: multiplicity of stationary states, stepwise changes in regimes, etc. Advances in catalysis: Catalysis and gas chemistry; catalysis and new energy technologies; biocatalysis; nanocatalysis; catalysis and new construction materials.History of the development of industrial catalysis.