Study on the Change Mechanism of Coal Oxidation Characteristics under Temperature and Stress

IF 0.8 4区 工程技术 Q4 CHEMISTRY, MULTIDISCIPLINARY
Zhihui Sun
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Abstract

In order to study the effect of stress and temperature on the spontaneous combustion behavior of deep coal, important conclusions are drawn through relevant experiments and analysis. It is found that stress can inhibit the ability of coal surface to adsorb oxygen, because it causes the pore structure of coal sample to compress, and the available area for oxygen adsorption is limited. Under the same temperature condition, the CO, CO2 emission and heat discharge increase with the increase of stress. When the stress is the same, the temperature increase also makes the CO, CO2 emission and heat discharge show the same change trend. The relationship between stress, temperature and heat release is polynomial, and the maximum heat release intensity appears at 120°C and 6 MPa stress. Further analysis shows that the weights of coal ash, moisture, fixed carbon, volatile matter, external stress, temperature and coal heat release are 0.1291, 0.1183, 0.3550, 0.1537, 0.2437, and 0.4419, respectively. The main factor affecting coal sample heat release is its own fixed carbon content. The influence of temperature on heat release from coal sample is greater than that of stress. These research results provide an important reference for further understanding of the oxidation characteristics of deep mining coal and related influencing factors.

Abstract Image

温度和应力作用下煤氧化特性变化机理的研究
为了研究应力和温度对深部煤自燃行为的影响,通过相关的实验和分析得出了重要的结论。研究发现,应力会抑制煤表面对氧的吸附能力,因为应力会使煤样的孔隙结构压缩,可用于吸附氧的面积受到限制。在相同温度条件下,随着应力的增加,CO、CO2排放量和放热量均增加。在应力相同的情况下,温度升高也使CO、CO2排放量和放热量呈现相同的变化趋势。应力、温度和放热之间呈多项式关系,放热强度在120℃、6 MPa应力下最大。进一步分析表明,煤灰分、水分、固定碳、挥发物、外部应力、温度和煤炭放热的权重分别为0.1291、0.1183、0.3550、0.1537、0.2437和0.4419。影响煤样放热的主要因素是煤样自身的固定碳含量。温度对煤样放热的影响大于应力的影响。这些研究结果为进一步认识深部开采煤的氧化特性及其影响因素提供了重要参考。
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来源期刊
Solid Fuel Chemistry
Solid Fuel Chemistry CHEMISTRY, MULTIDISCIPLINARY-ENERGY & FUELS
CiteScore
1.10
自引率
28.60%
发文量
52
审稿时长
6-12 weeks
期刊介绍: The journal publishes theoretical and applied articles on the chemistry and physics of solid fuels and carbonaceous materials. It addresses the composition, structure, and properties of solid fuels. The aim of the published articles is to demonstrate how novel discoveries, developments, and theories may be used in improved analysis and design of new types of fuels, chemicals, and by-products. The journal is particularly concerned with technological aspects of various chemical conversion processes and includes papers related to geochemistry, petrology and systematization of fossil fuels, their beneficiation and preparation for processing, the processes themselves, and the ultimate recovery of the liquid or gaseous end products.
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