Experiment and prediction on performance of all-solid-waste foam ceramics

IF 3.8 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES
Yongxin Li, Changwang Yan, Ju Zhang, Junqing Li, Jihui Zhao, Fei Cao
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Abstract

Integrating carbide slag (CS), fly ash, and coal gangue to synthesize fully solid waste foam ceramics provides a viable solid waste management solution. This study analyzes sintering parameters and CS dosage effects on foam ceramic properties: physical traits, pore structure, micromorphology, mineral phases, and sintering behavior. The findings reveal that the carbon content in coal gangue and the Fe2O3 present in fly ash function as foaming agents, facilitating a reaction that generates CO2, thereby inducing a foaming effect. Upon calcination, CS yields CaO, which acts as a flux; an increase in CS content correlates with a reduction in the viscosity of the foam ceramic melt, a decrease in porosity, and an enhancement in thermal conductivity. In terms of sintering parameters, higher sintering temperatures and longer dwell times are conducive to the foaming of ceramics. However, excessively high temperatures and prolonged durations may compromise the structural integrity of the foam ceramics. Optimal performance occurs at 29 wt% CS content, sintered at 1290 °C for 20 min. Additionally, to address challenges from variable solid waste composition and complex performance evaluation, AI algorithms predicted foam ceramic properties with high accuracy, achieving an R² of 0.95.

Abstract Image

全固废泡沫陶瓷的性能试验与预测
利用电石渣、粉煤灰、煤矸石合成全固废泡沫陶瓷提供了一种可行的固废治理方案。本研究分析了烧结参数和CS用量对泡沫陶瓷物理特性、孔隙结构、微观形貌、矿物相和烧结行为的影响。研究结果表明,煤矸石中的碳含量和粉煤灰中存在的Fe2O3起到发泡剂的作用,促进了生成CO2的反应,从而产生了发泡效果。煅烧后,CS生成CaO, CaO作为助熔剂;CS含量的增加与泡沫陶瓷熔体粘度的降低、孔隙率的降低和导热性的增强有关。在烧结参数方面,较高的烧结温度和较长的停留时间有利于陶瓷的发泡。然而,过高的温度和持续时间可能会损害泡沫陶瓷的结构完整性。当CS含量为29 wt%时,烧结温度为1290°C,烧结时间为20分钟。此外,为了应对固体废物组成变化和复杂性能评估的挑战,人工智能算法对泡沫陶瓷性能的预测精度很高,R²为0.95。
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来源期刊
CiteScore
5.30
自引率
16.10%
发文量
205
审稿时长
4.8 months
期刊介绍: The Journal of Material Cycles and Waste Management has a twofold focus: research in technical, political, and environmental problems of material cycles and waste management; and information that contributes to the development of an interdisciplinary science of material cycles and waste management. Its aim is to develop solutions and prescriptions for material cycles. The journal publishes original articles, reviews, and invited papers from a wide range of disciplines related to material cycles and waste management. The journal is published in cooperation with the Japan Society of Material Cycles and Waste Management (JSMCWM) and the Korea Society of Waste Management (KSWM).
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