Spin-lattice coupling induced chiral phonons and their signature in Raman Circular Dichroism

Abstract

Recent Raman experiments on the Kitaev material α-RuCl3 have reported a finite Raman circular dichroism (RCD), revealing chiral phonon behavior not expected from lattice symmetry alone. To explain this observation, we develop a diagrammatic framework for the spin–phonon-coupled Kitaev model. We demonstrate that bare phonons contribute no RCD, but coupling to the chiral spin excitation continuum under an applied magnetic field renormalizes the phonon propagator, mixing real polarization eigenvectors into complex superpositions with finite angular momentum. This interaction-induced modification generates a nonzero RCD accompanied by characteristic Fano line shapes in the Raman response, reflecting interference between discrete phonons and the continuum. The resulting signal grows with magnetic field strength, consistent with experiment, and directly tracks the field-induced chirality of the spin sector. More broadly, our results establish RCD as a powerful probe of interaction-induced chiral phonons in correlated quantum materials.