Oxidation of Tar over Manganese Catalysts

IF 1.1 4区 工程技术 Q3 CHEMISTRY, ORGANIC
Vagif M. Abbasov, Lala M. Afandiyeva, Yutta P. Cherepnova, Gunay G. Nasibova, Saida F. Ahmadbayova, Nushaba M. Aliyeva, Anton S. Lyadov, Emin I. Azizbayli
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引用次数: 0

Abstract

This study investigates the effects of a catalytic modifier based on manganese salts of natural petroleum acids on the performance of tar oxidation and the properties of the resulting bitumen product. It is demonstrated that, compared to noncatalytic tar oxidation, the proposed catalyst not only more than doubles the process intensity but also significantly improves the product quality. IR spectroscopy showed that an optimal catalyst loading (0.3 wt %) provides an appreciable increase in the degree of oxidation (>30%) and aromaticity (>10%) of the bitumen, while preserving its aliphatic components, which act as a plasticizer. The formation of polar carbonyl groups enhances the adhesive capacity of the product, whereas the increased aromaticity favors its thermal stability as a binder. The study results validate the effectiveness of the proposed catalytic approach for producing bitumen with improved performance characteristics.

Abstract Image

锰催化剂上焦油的氧化
研究了天然石油酸锰盐催化改性剂对焦油氧化性能和沥青产品性能的影响。结果表明,与非催化氧化焦油相比,该催化剂不仅使工艺强度提高了一倍以上,而且显著提高了产品质量。红外光谱分析表明,最佳催化剂负载(0.3 wt %)可显著提高沥青的氧化度(30%)和芳香度(10%),同时保留沥青的脂肪族成分,这些脂肪族成分起到增塑剂的作用。极性羰基的形成增强了产物的粘接能力,而芳香性的增加有利于其作为粘合剂的热稳定性。研究结果验证了所提出的催化生产沥青的有效性,并改善了沥青的性能特征。
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来源期刊
Petroleum Chemistry
Petroleum Chemistry 工程技术-工程:化工
CiteScore
2.50
自引率
21.40%
发文量
102
审稿时长
6-12 weeks
期刊介绍: Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas. Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.
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