Synthesis and Structure of Two New Metal-Organic Frameworks: [Cd3(bdc)2.4(2-Ibdc)0.6(DMF)4] and [Cd(2-Ibdc)(bipy)]·1.2(DMF)

IF 1.5 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Structural Chemistry Pub Date : 2026-06-09 DOI:10.1134/S0022476626050045

A. S. Zaguzin, M. A. Bondarenko, A. V. Zaitsev, N. A. Korobeinikov, R. V. Redkin, E. A. Pilyukova, S. A. Adonin

引用次数: 0

Abstract

The Cd(II) coordination polymers [Cd₃(bdc)_2.4(2-Ibdc)_0.6(DMF)₄] (1) and [Cd(2-Ibdc)(bipy)]·1.2DMF (2·1.2DMF) are obtained. In compound 1, partial replacement of terephthalic acid (bdc) molecules by 2-iodoterephthalic acid (2-Ibdc) molecules is achieved. The structure of compound 2·1.2DMF exhibits a disorder of 2-Ibdc and 4,4′-bipyridine molecules. The structures of the compounds are determined by single crystal X-ray diffraction analysis.

查看原文本刊更多论文

两种新型金属有机骨架[Cd3(bdc)2.4(2-Ibdc)0.6(DMF)4]和[Cd(2-Ibdc)(bipy)]·1.2（DMF）的合成与结构

得到了Cd（II）配位聚合物[Cd3(bdc)2.4(2- ibdc)0.6(DMF)4](1)和[Cd(2- ibdc)(bipy)]·1.2DMF(2·1.2DMF)]。在化合物1中，2-碘对苯二甲酸（2-Ibdc）分子部分取代了对苯二甲酸（bdc）分子。化合物2·1.2DMF的结构表现为2- ibdc和4,4′-联吡啶分子的无序性。化合物的结构由单晶x射线衍射分析确定。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of Structural Chemistry 化学-无机化学与核化学

CiteScore

1.60

自引率

12.50%

发文量

142

审稿时长

8.3 months

期刊介绍： Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.