Structural and Spectroscopic Studies of (NH4Cl)[Ni2(H2O)6(Se2O5)Cl2] and (RbBr)[Ni(HSeO3)2(H2SeO3)0.5(H2O)0.5]—New Members of the Transition Metal (Hydro)Selenite-Halide Family

IF 0.5 4区材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY

Inorganic Materials Pub Date : 2026-05-19 DOI:10.1134/S0020168526700433

D. O. Charkin, A. M. Gorianskii, V. Yu. Grishaev, A. A. Kompanchenko, A. N. Gosteva, S. M. Aksenov

{"title":"Structural and Spectroscopic Studies of (NH4Cl)[Ni2(H2O)6(Se2O5)Cl2] and (RbBr)[Ni(HSeO3)2(H2SeO3)0.5(H2O)0.5]—New Members of the Transition Metal (Hydro)Selenite-Halide Family","authors":"D. O. Charkin, A. M. Gorianskii, V. Yu. Grishaev, A. A. Kompanchenko, A. N. Gosteva, S. M. Aksenov","doi":"10.1134/S0020168526700433","DOIUrl":null,"url":null,"abstract":"Single crystals of two new nickel diselenite/hydroselenite halides, (NH4Cl)[Ni2(H2O)6(Se2O5)Cl2] (1) and (RbBr)[Ni(HSeO3)2(H2SeO3)0.5(H2O)0.5] (2), were produced upon evaporation of aqueous solutions containing nickel and rubidium (ammonium) halide and selenious acid. Both structures correspond to new structure types. That of 1 is comprised of neutral [Ni2(H2O)6(Se2O5)Cl2] chains aligned into weakly bonded layers linked by hydrogen bonding. The ammonium cations and extra chloride anions reside in the interlayer space. The structure of 2 belong to the family of the so-called “layered hydroselenites” with neutral [Ni(HSeO3)2] layers decorated by Br– and linked by H2SeO3 molecules into a weak hydrogen-bonded framework with Rb+ cations filling the voids therein. Under the same conditions, no analogies have hitherto been found to the products formed in related systems containing copper, cobalt, or zinc halides.","PeriodicalId":585,"journal":{"name":"Inorganic Materials","volume":"61 7-15","pages":"664 - 674"},"PeriodicalIF":0.5000,"publicationDate":"2026-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S0020168526700433","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

Single crystals of two new nickel diselenite/hydroselenite halides, (NH₄Cl)[Ni₂(H₂O)₆(Se₂O₅)Cl₂] (1) and (RbBr)[Ni(HSeO₃)₂(H₂SeO₃)_0.5(H₂O)_0.5] (2), were produced upon evaporation of aqueous solutions containing nickel and rubidium (ammonium) halide and selenious acid. Both structures correspond to new structure types. That of 1 is comprised of neutral [Ni₂(H₂O)₆(Se₂O₅)Cl₂] chains aligned into weakly bonded layers linked by hydrogen bonding. The ammonium cations and extra chloride anions reside in the interlayer space. The structure of 2 belong to the family of the so-called “layered hydroselenites” with neutral [Ni(HSeO₃)₂] layers decorated by Br^– and linked by H₂SeO₃ molecules into a weak hydrogen-bonded framework with Rb⁺ cations filling the voids therein. Under the same conditions, no analogies have hitherto been found to the products formed in related systems containing copper, cobalt, or zinc halides.

Abstract Image

查看原文本刊更多论文

（NH4Cl）[Ni2(H2O)6(Se2O5)Cl2]和（RbBr）[Ni(HSeO3)2(H2SeO3)0.5(H2O)0.5] -过渡金属（氢）亚硒酸盐族新成员的结构和光谱研究

用含镍、卤化铷（铵）和亚硒酸的水溶液蒸发制备了两种新型镍二硒酸盐/氢亚硒酸盐卤化物（NH4Cl）[Ni2(H2O)6(Se2O5)Cl2](1)和（RbBr）[Ni(HSeO3)2(H2SeO3)0.5(H2O)0.5](2)单晶。这两种结构都对应于新的结构类型。其中1是由中性[Ni2(H2O)6(Se2O5)Cl2]链排列成由氢键连接的弱键层组成。铵离子和多余的氯离子存在于层间空间。2的结构属于所谓的“层状氢亚硒酸盐”家族，具有中性的[Ni(HSeO3)2]层，由Br -装饰，并由H2SeO3分子连接成弱氢键框架，其中Rb+阳离子填充其中的空隙。在相同的条件下，迄今为止还没有发现在含有铜、钴或卤化锌的相关体系中形成的类似产物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Inorganic Materials 工程技术-材料科学：综合

CiteScore

1.40

自引率

25.00%

发文量

审稿时长

3-6 weeks

期刊介绍： Inorganic Materials is a journal that publishes reviews and original articles devoted to chemistry, physics, and applications of various inorganic materials including high-purity substances and materials. The journal discusses phase equilibria, including P–T–X diagrams, and the fundamentals of inorganic materials science, which determines preparatory conditions for compounds of various compositions with specified deviations from stoichiometry. Inorganic Materials is a multidisciplinary journal covering all classes of inorganic materials. The journal welcomes manuscripts from all countries in the English or Russian language.