TiNb Films Formed by a Vacuum-Arc Plasma-Assisted Method: Structure and Properties

IF 0.5 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY
Yu. F. Ivanov, N. A. Prokopenko, E. A. Petrikova, N. N. Koval’
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Abstract

Metastable titanium-based alloys containing niobium, tantalum, zirconium, molybdenum, and a number of other elements (β-Ti alloys) have a relatively low Young’s modulus and are widely used in medicine. The aim of this work is to analyze the structure and properties of Ti–Nb alloys in the form of thin (2.5–3 μm) films deposited during simultaneous vacuum-arc plasma-assisted sputtering of two cathodes. Films with various relative contents of titanium and niobium atoms are shown to be formed by varying the metal cathode evaporator currents. The films are found to have a columnar multilayered structure. The thickness of niobium-rich layers is 3–4 nm and that of titanium-rich layers, 7–35 nm. The main phase of the films is β-TiNb. The microhardness and wear parameter of the deposited films are determined. The dependence of the microhardness and wear parameter on the ratio of the metal cathode evaporator currents has been revealed. The relation between the microhardness and wear resistance of the TiNb films has been found, and it can be used to predict the behavior of the material under operating conditions.

Abstract Image

真空弧等离子体辅助法制备TiNb薄膜:结构与性能
亚稳态钛基合金含有铌、钽、锆、钼和其他一些元素(β-钛合金),杨氏模量相对较低,在医学上得到广泛应用。本研究的目的是分析在真空弧等离子体辅助溅射过程中沉积的Ti-Nb合金(2.5 ~ 3 μm)薄膜的结构和性能。通过改变金属阴极蒸发器电流,可以形成钛和铌原子相对含量不同的薄膜。发现薄膜具有柱状多层结构。富铌层厚度为3 ~ 4 nm,富钛层厚度为7 ~ 35 nm。薄膜的主要相是β-TiNb。测定了沉积膜的显微硬度和磨损参数。揭示了金属阴极蒸发器电流比对合金显微硬度和磨损参数的影响。发现了TiNb薄膜的显微硬度与耐磨性之间的关系,可以用来预测材料在工作条件下的行为。
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来源期刊
Inorganic Materials
Inorganic Materials 工程技术-材料科学:综合
CiteScore
1.40
自引率
25.00%
发文量
80
审稿时长
3-6 weeks
期刊介绍: Inorganic Materials is a journal that publishes reviews and original articles devoted to chemistry, physics, and applications of various inorganic materials including high-purity substances and materials. The journal discusses phase equilibria, including P–T–X diagrams, and the fundamentals of inorganic materials science, which determines preparatory conditions for compounds of various compositions with specified deviations from stoichiometry. Inorganic Materials is a multidisciplinary journal covering all classes of inorganic materials. The journal welcomes manuscripts from all countries in the English or Russian language.
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