RNHSO2F as Reliable Azasulfene Precursors for the Construction of Sulfamates

IF 2.2 4区化学 Q2 CHEMISTRY, ORGANIC

Synthesis-Stuttgart Pub Date : 2024-12-26 DOI:10.1055/a-2508-3355

Long Xu, Jiajia Dong, Taijie Guo, Wei Wang

引用次数: 2

Abstract

Abstract The utilization of NH-sulfamoyl fluorides (RNHSO2F) as reliable SuFEx synthons for the construction of various sulfamate esters is reported. By using potassium fluoride as base, we were able to convert RNHSO2F into azasulfene intermediates under mild conditions and guarantee their further efficient ligation with phenols and alcohols.

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RNHSO2F作为构建氨基磺酸盐的可靠偶氮磺胺前体

摘要报道了利用nh -磺胺酰氟（RNHSO2F）作为可靠的SuFEx合成物，构建各种磺胺酸酯。以氟化钾为碱，我们能够在温和的条件下将RNHSO2F转化为偶氮磺胺中间体，并保证它们与酚类和醇类进一步有效的结合。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Synthesis-Stuttgart 化学-有机化学

CiteScore

4.50

自引率

7.70%

发文量

435

审稿时长

1 months

期刊介绍： SYNTHESIS is an international full-paper journal devoted to the advancement of the science of chemical synthesis. It covers all fields of organic chemistry involving synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines. SYNTHESIS provides dependable research results with detailed and reliable experimental procedures and full characterization of all important new products as well as scientific primary data.