Phenanthrolines as Energy Transfer Photocatalysts for the E → Z Isomerization of Alkenes

IF 2.2 4区化学 Q2 CHEMISTRY, ORGANIC

Synthesis-Stuttgart Pub Date : 2024-12-16 DOI:10.1055/a-2502-8374

Dequn Sun, Kun‐Quan Chen, Xiang-Yu Chen, Xiaobo Chen, Jia Zhang

引用次数: 0

Abstract

Abstract Phenanthrolines have been widely employed as chelating ligands for transition metals. Herein, this study investigates the utility of substituted o-phenanthrolines as independent photosensitizers for the E → Z isomerization of alkenes. The findings underscore the versatility of o-phenanthrolines, providing a straightforward, metal-free, and cost-effective method for synthesizing Z-alkenes.

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邻菲罗啉作为烯烃E→Z异构化的能量转移光催化剂

摘要菲罗啉类化合物作为过渡金属的螯合配体已被广泛应用。本文研究了取代邻菲罗啉作为独立光敏剂在烯烃E→Z异构化反应中的应用。这一发现强调了邻菲罗啉的多功能性，为合成z -烯烃提供了一种简单、无金属、经济的方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Synthesis-Stuttgart 化学-有机化学

CiteScore

4.50

自引率

7.70%

发文量

435

审稿时长

1 months

期刊介绍： SYNTHESIS is an international full-paper journal devoted to the advancement of the science of chemical synthesis. It covers all fields of organic chemistry involving synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines. SYNTHESIS provides dependable research results with detailed and reliable experimental procedures and full characterization of all important new products as well as scientific primary data.