Cobalt-Catalyzed Regioselective Hydroformylation of Allylic Alcohol Esters

IF 2.2 4区化学 Q2 CHEMISTRY, ORGANIC

Synthesis-Stuttgart Pub Date : 2025-01-11 DOI:10.1055/a-2515-0227

Wenxin Lu, Qinglei Chong, Fanke Meng, Zhao Du

引用次数: 0

Abstract

Abstract Aliphatic aldehydes are important building blocks in organic synthesis due to their high reactivity and versatility. Herein, we report a simple, mild and efficient method for the hydroformylation of allyl alcohol esters under cobalt catalysis. This procedure offers good functional group tolerance, moderate to good product yields and exclusive chemo- and regioselectivity, making it an attractive method to prepare aldehydes with linear selectivity.

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钴催化丙烯醇酯的区域选择性氢甲酰化反应

脂肪族醛因其高反应性和多功能性而成为有机合成的重要组成部分。本文报道了一种简单、温和、高效的钴催化丙烯醇酯氢甲酰化反应方法。该方法具有良好的官能团耐受性、中等至良好的产物收率和独特的化学选择性和区域选择性，是制备具有线性选择性的醛的一种有吸引力的方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Synthesis-Stuttgart 化学-有机化学

CiteScore

4.50

自引率

7.70%

发文量

435

审稿时长

1 months

期刊介绍： SYNTHESIS is an international full-paper journal devoted to the advancement of the science of chemical synthesis. It covers all fields of organic chemistry involving synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines. SYNTHESIS provides dependable research results with detailed and reliable experimental procedures and full characterization of all important new products as well as scientific primary data.