π-Extended dipyrrolopyrazines as multifunctional materials

Organic chemistry frontiers : an international journal of organic chemistry Pub Date : 2026-06-16 Epub Date: 2026-04-27 DOI:10.1039/d6qo00350h

Justin Kahle , Niklas J. Hermann , Martin C. Dietl , Patrick D. Römgens , Kim J. Warth , Christopher Hüßler , Alexandra V. Mackenroth , Fabian Baier , Ute Zschieschang , Petra Krämer , Frank Rominger , Matthias Rudolph , Hagen Klauk , Jana Zaumseil , A. Stephen K. Hashmi

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Abstract

Here, we report a convergent synthetic strategy employing a gold-catalyzed cyclization to construct novel π-extended dipyrrolopyrazine () derivatives in a modular fashion. The robust design of s ensures high thermal stability, excellent oxidation resistance, and adaptability for integration into organic thin-film transistors and photoluminescent devices. Systematic exploration of substitution patterns revealed insights into structure–property relationships, particularly the influence of isosteric CH/N exchange. These findings establish s as a versatile platform for multifunctional materials, offering pathways for innovations in organic electronics.

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π-扩展双吡咯吡嗪作为多功能材料

在这里，我们报告了一种收敛合成策略，采用金催化环化以模块化方式构建新的π-扩展双吡咯吡嗪（EDPP）衍生物。EDPPs的坚固设计确保了高热稳定性，优异的抗氧化性以及集成到有机薄膜晶体管和光致发光器件中的适应性。对取代模式的系统探索揭示了对结构-性质关系的见解，特别是对等均衡CH/N交换的影响。这些发现确立了EDPPs作为多功能材料的通用平台，为有机电子学的创新提供了途径。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Organic chemistry frontiers : an international journal of organic chemistry

CiteScore

7.80

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0.00%

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