Liquidus Projection of the Cr-Nb-V System

IF 2 4区 材料科学 Q4 CHEMISTRY, PHYSICAL
J. V. Luiz, N. Chaia, A. A. A. P. Silva, C. A. Nunes, G. C. Coelho
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引用次数: 0

Abstract

Phase equilibria in the Cr-Nb-V system have an important role in the development of new materials for future aerospace applications. However, the available data on this system remains limited. Therefore, this work proposes, for the first time, a liquidus projection based on the microstructural characterization of as-cast alloys. A total of twenty-seven alloys were produced and their microstructures characterized by using scanning electron microscopy (SEM) to observe the phase morphology, energy dispersive spectroscopy (EDS) and x-ray diffractometry (XRD) for phase identification. The results show a predominant primary precipitation of the BCC phase, along with two distinct regions of primary precipitation of intermetallic phases. One of these is the Laves C15 phase, originating from the Cr-Nb binary system, while the other is a phase that was identified as Φ which transforms into C15 during cooling to room temperature.

Cr-Nb-V系的液相投影
Cr-Nb-V体系的相平衡对未来航空航天应用新材料的开发具有重要作用。但是,关于这一系统的现有数据仍然有限。因此,这项工作首次提出了基于铸态合金微观组织表征的液相线投影。采用扫描电子显微镜(SEM)观察相形貌,能谱仪(EDS)和x射线衍射仪(XRD)进行相鉴定,对27种合金进行了显微组织表征。结果表明,BCC相主要为初生析出,金属间相有两个明显的初生析出区。其中一个是来自Cr-Nb双星系统的Laves C15相,而另一个是在冷却到室温时转变为C15的Φ相。
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来源期刊
Journal of Phase Equilibria and Diffusion
Journal of Phase Equilibria and Diffusion 工程技术-材料科学:综合
CiteScore
2.50
自引率
7.10%
发文量
70
审稿时长
1 months
期刊介绍: The most trusted journal for phase equilibria and thermodynamic research, ASM International''s Journal of Phase Equilibria and Diffusion features critical phase diagram evaluations on scientifically and industrially important alloy systems, authored by international experts. The Journal of Phase Equilibria and Diffusion is critically reviewed and contains basic and applied research results, a survey of current literature and other pertinent articles. The journal covers the significance of diagrams as well as new research techniques, equipment, data evaluation, nomenclature, presentation and other aspects of phase diagram preparation and use. Content includes information on phenomena such as kinetic control of equilibrium, coherency effects, impurity effects, and thermodynamic and crystallographic characteristics. The journal updates systems previously published in the Bulletin of Alloy Phase Diagrams as new data are discovered.
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