Structural Features and Transport Properties of Hybrid Membranes Based on Polylactide with Additives of Star-Shaped Macromolecules

IF 1.2 Q4 CHEMISTRY, PHYSICAL
A. Yu. Pulyalina, M. E. Gogunov, O. R. Karpukhin, I. S. Kuryndin, A. V. Aksentiev, G. A. Polotskaya
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Abstract

Using biodegradable polymer, polylactide, two composites containing 5 wt % fillers, which are star-shaped macromolecules with a branching center, C60 fullerene, and grafted polymer arms of various nature, have been synthesized. The structural features and mechanical properties of the prepared film membranes were studied. The density and contact angles were determined to characterize the physical properties. The transport properties were studied by measuring the permeability of He, O2, N2, and CО2. It is shown that the incorporation of star-shaped modifiers into the polylactide matrix leads to a slight decrease in the permeability coefficients for all gases, but the ideal selectivity for O2/N2, Hе/N2, and CО2/N2 gas pairs increases.

Abstract Image

星形大分子添加剂聚乳酸杂化膜的结构特征及输运性能
以生物可降解聚合物聚丙交酯为原料,合成了两种含5 wt %填料的星形大分子、具有分支中心的C60富勒烯和各种性质的接枝聚合物臂复合材料。对制备的膜的结构特征和力学性能进行了研究。测定了密度和接触角来表征材料的物理性质。通过测量He、O2、N2和CО2的渗透率来研究其输运性质。结果表明,在聚丙交酯基体中加入星形改性剂后,所有气体的渗透系数都略有降低,但对O2/N2、h_ /N2和CО2/N2气体对的理想选择性增加。
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来源期刊
CiteScore
3.10
自引率
31.20%
发文量
38
期刊介绍: The journal Membranes and Membrane Technologies publishes original research articles and reviews devoted to scientific research and technological advancements in the field of membranes and membrane technologies, including the following main topics:novel membrane materials and creation of highly efficient polymeric and inorganic membranes;hybrid membranes, nanocomposites, and nanostructured membranes;aqueous and nonaqueous filtration processes (micro-, ultra-, and nanofiltration; reverse osmosis);gas separation;electromembrane processes and fuel cells;membrane pervaporation and membrane distillation;membrane catalysis and membrane reactors;water desalination and wastewater treatment;hybrid membrane processes;membrane sensors;membrane extraction and membrane emulsification;mathematical simulation of porous structures and membrane separation processes;membrane characterization;membrane technologies in industry (energy, mineral extraction, pharmaceutics and medicine, chemistry and petroleum chemistry, food industry, and others);membranes and protection of environment (“green chemistry”).The journal has been published in Russian already for several years, English translations of the content used to be integrated in the journal Petroleum Chemistry. This journal is a split off with additional topics.
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