O. M. Gavrilyuk, S. A. Semenova, D. R. Nurmukhametov
{"title":"Changes in the Characteristics of Pitch on Modifying Coal Tar by Ozone in Chloroform","authors":"O. M. Gavrilyuk, S. A. Semenova, D. R. Nurmukhametov","doi":"10.3103/S1068364X25601222","DOIUrl":null,"url":null,"abstract":"<p>The quality of coal tar pitch samples obtained from industrial coal tar and tar modified by means of ozone in chloroform is compared. The structure of the pitch is determined by means of standard chemical analysis of the pitch, IR and NMR spectroscopy, and elemental and thermogravimetric analysis. The ozonolytic modification of coal tar in a neutral solvent (chloroform) increases the yield of pitch, its content of the α fraction (the sum of the α<sub>1</sub> and α<sub>2</sub> fractions), the softening point, and the yield of volatiles.</p>","PeriodicalId":519,"journal":{"name":"Coke and Chemistry","volume":"68 10","pages":"852 - 857"},"PeriodicalIF":0.6000,"publicationDate":"2026-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coke and Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.3103/S1068364X25601222","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The quality of coal tar pitch samples obtained from industrial coal tar and tar modified by means of ozone in chloroform is compared. The structure of the pitch is determined by means of standard chemical analysis of the pitch, IR and NMR spectroscopy, and elemental and thermogravimetric analysis. The ozonolytic modification of coal tar in a neutral solvent (chloroform) increases the yield of pitch, its content of the α fraction (the sum of the α1 and α2 fractions), the softening point, and the yield of volatiles.
期刊介绍:
The journal publishes scientific developments and applications in the field of coal beneficiation and preparation for coking, coking processes, design of coking ovens and equipment, by-product recovery, automation of technological processes, ecology and economics. It also presents indispensable information on the scientific events devoted to thermal rectification, use of smokeless coal as an energy source, and manufacture of different liquid and solid chemical products.