Comparative photochemical flow synthesis of ketenimines via Hg-lamp and UV-C LED irradiation

IF 2.9 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Adam Cruise, Rémy Broersma, Frouke van den Berg and Marcus Baumann
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引用次数: 0

Abstract

The use of novel UV-C LEDs emitting monochromatic light at 265 nm is reported for the continuous flow synthesis of ketenimines from isoxazoles. The resulting flow process is compared to the use of a traditional Hg-lamp showing that substantial improvements in reaction performance and efficiency are obtained demonstrating the value of these high-power UV-C LED modules (up to 40 W of input power).

Abstract Image

hg灯与UV-C LED光化学流合成氯胺酮的比较研究
报道了利用新型UV-C发光二极管发射265 nm单色光,以异恶唑为原料连续流合成氯胺酮。将所产生的流动过程与使用传统的hg灯进行比较,表明在反应性能和效率方面获得了实质性的改进,证明了这些高功率UV-C LED模块(高达40 W输入功率)的价值。
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来源期刊
Reaction Chemistry & Engineering
Reaction Chemistry & Engineering Chemistry-Chemistry (miscellaneous)
CiteScore
6.60
自引率
7.70%
发文量
227
期刊介绍: Reaction Chemistry & Engineering is a new journal reporting cutting edge research into all aspects of making molecules for the benefit of fundamental research, applied processes and wider society. From fundamental, molecular-level chemistry to large scale chemical production, Reaction Chemistry & Engineering brings together communities of chemists and chemical engineers working to ensure the crucial role of reaction chemistry in today’s world.
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