Dual recovery and utilization strategy for metallic and non‐metallic components in waste mobile phone circuit boards

IF 2.3 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL
Hongfei Sun, Q. Deng, Zhengxin Peng, Chunyang Yu, Fan Liu, Xuemei Tan, Xuemei Zhang, Qiaoling Liu, Shanshan Mao, Jie Zhang
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引用次数: 0

Abstract

Abstract Waste mobile phone circuit boards (WMPCBs), a critical component of waste mobile phones, contain substantial metallic components (MCs) and non‐metallic components (NMCs), serving as a potential secondary resource. MCs and NMCs were efficiently separated via ultrasound‐enhanced gravity separation. The MCs were subsequently subjected to ultrasonic‐assisted leaching using glutathione (GSH), glycine (GG), and glycyl‐L‐glutamine (GLG), followed by solvent displacement crystallization to synthesize copper‐chelated small peptides (CCPs). X‐ray fluorescence spectroscopy (XRF), x‐ray diffraction (XRD), and energy‐dispersive x‐ray spectroscopy (EDS) confirmed that the elemental compositions of three CCPs aligned with theoretical predictions. Agronomic evaluations demonstrated that CCPs significantly enhanced seed germination rates (reaching 100% for rice and sorghum) and slightly increased seedling height (over 1 cm for rice and maize), outperforming the control and conventional copper fertilizer groups by 33.3% in germination efficiency. Simultaneously, KH550‐modified NMCs were combined with nano‐SiO 2 , nano‐ZnO, and graphite in varying proportions to fabricate multiscale filler/epoxy resin (EP) composites, and their mechanical properties were systematically investigated. Results demonstrated that controlling the content of these fillers significantly enhanced the composites' impact strength and fracture toughness, broadening their potential for applications requiring tailored mechanical performance.
废手机电路板中金属和非金属成分的双重回收利用策略
废旧手机电路板(wmpcb)是废旧手机的重要组成部分,含有大量的金属成分(MCs)和非金属成分(NMCs),是潜在的二次资源。超声增强重力分离法可有效分离MCs和NMCs。随后用谷胱甘肽(GSH)、甘氨酸(GG)和甘酰L -谷氨酰胺(GLG)对MCs进行超声辅助浸出,然后用溶剂置换结晶合成铜螯合小肽(CCPs)。X射线荧光光谱(XRF)、X射线衍射(XRD)和能量色散X射线光谱(EDS)证实了三种ccp的元素组成与理论预测一致。农艺评价表明,CCPs显著提高了种子发芽率(水稻和高粱达到100%),幼苗高度略有增加(水稻和玉米超过1 cm),发芽效率比对照和常规铜肥组高33.3%。同时,以不同比例的纳米二氧化硅、纳米氧化锌和石墨与KH550改性nmc复合制备了多尺度填料/环氧树脂(EP)复合材料,并对其力学性能进行了系统的研究。结果表明,控制这些填料的含量可以显著提高复合材料的冲击强度和断裂韧性,扩大其在需要定制力学性能的应用领域的潜力。
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来源期刊
Environmental Progress & Sustainable Energy
Environmental Progress & Sustainable Energy 环境科学-工程:化工
CiteScore
5.00
自引率
3.60%
发文量
231
审稿时长
4.3 months
期刊介绍: Environmental Progress , a quarterly publication of the American Institute of Chemical Engineers, reports on critical issues like remediation and treatment of solid or aqueous wastes, air pollution, sustainability, and sustainable energy. Each issue helps chemical engineers (and those in related fields) stay on top of technological advances in all areas associated with the environment through feature articles, updates, book and software reviews, and editorials.
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