Research on Aging Characteristics and Interfacial Adhesion Performance of Polyurethane-Modified Asphalt

Abstract

Polyurethane (PU), owing to its superior physicochemical properties, is considered an ideal modifier for asphalt. To improve the mechanical performance and service durability of asphalt pavements, PU-modified asphalts with varying dosages were prepared and evaluated through laboratory experiments and molecular dynamics simulations. Rheological, thermodynamic, and mechanical tests, as well as asphalt–aggregate adhesion energy calculations, were conducted to elucidate the modification mechanism, aging resistance, and interfacial behavior. The results showed that PU incorporation significantly enhanced rutting resistance at high temperatures, flexibility at low temperatures, and overall load-bearing capacity. Under ultraviolet and long-term aging, PU-modified asphalts exhibited notably lower performance degradation than base asphalt. At the molecular level, PU absorbed light fractions and formed a cross-linked network, reducing the free volume fraction and strengthening resistance to deformation. Moreover, PU substantially improved asphalt–aggregate adhesion energy, thereby reinforcing interfacial bonding. These findings provide theoretical insights and practical guidance for the optimal design and engineering application of PU-modified asphalt.