Study on the Performance of BiOCl Photocatalyst for Degradation of Tetracycline Hydrochloride

Abstract

Tetracycline hydrochloride (TC-HCl) is widely used in the prevention and treatment of human/animal bacterial infection due to its good antibacterial activity. However, because of its high hydrophilicity and low volatility, TC-HCl can enter the natural water body through various ways and exist in it statically for a long time, which then causes environmental toxicity and even threatens human health. Photocatalysis, which can use free, clean and sustainable solar energy to provide power, achieves the conversion of solar energy to chemical energy and is a promising green technology for solving global environmental and energy challenges. BiOCl has suitable valence/conduction potential and good stability and hierarchical structure, which contributes to smooth transfer of surface charge. BiOCl photocatalyst materials with deionized water, anhydrous ethanol (EtOH), and ethylene glycol (EG) as solvents were prepared by using different viscosity solutions as reaction media. The characterization results showed that the type of solvent is what mainly affected the morphology and absorption intensity of the photocatalyst. BiOCl prepared with EG as solvent has the best photocatalytic degradation performance of TC-HCl, and the removal rate can reach 76% after 60 min of visible light irradiation. Its strong light response intensity and unique spherical structure contribute to the enhancement of photocatalytic activity.