Thermodynamics of Sorption–Desorption Cycles of a Temperature-Controlled Conformal Methane Accumulator Loaded with a Compacted Carbon Adsorbent

IF 0.8 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING
I. D. Shelyakin, I. E. Menshchikov, S. S. Chugaev, A. V. Shkolin, A. A. Fomkin
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引用次数: 0

Abstract

Methane adsorbed natural gas (ANG) is a promising technology applicable to gas storage and transportation. ANG provides higher capacity at relatively low operating pressures compared to CNG, as well as increased fire and explosion safety and energy efficiency of the charge/discharge processes. This allows us to move to new engineering principles for gas accumulators based on conformal designs instead of cylindrical cylinders. A scaled natural gas accumulator (SNGA) of a conformal design with a volume of 24 L loaded with a compacted industrial carbon adsorbent, KS-HAM, was developed, and the comprehensive study of its cyclic operation was carried out. As part of the experiment, the cyclic operation of SNGA was studied under conditions of high-speed charge (up to 2 min) and slow discharge with gas flow rates of 5 and 10 L (NTP)1/min in two modes: with active temperature control and natural convection. For theoretical studies of the cyclic operation of the SNGA, a lumped parameter model was developed and verified using experimental data. The investigations resulted in the characteristics of the cyclic operation of the SNGA that are essential for the purposes of actual usage on passenger vehicles.

Abstract Image

负载压实碳吸附剂的温控适形甲烷蓄能器吸附-解吸循环热力学
甲烷吸附天然气是一种很有前途的天然气储运技术。与CNG相比,ANG在相对较低的操作压力下提供更高的容量,并且提高了充放电过程的防火和爆炸安全性以及能源效率。这使我们能够转向基于保形设计而不是圆柱体的气体蓄能器的新工程原理。研制了一种体积为24 L的保形设计的加气罐(SNGA),并对其循环运行进行了综合研究,该加气罐装载了工业碳吸附剂KS-HAM。作为实验的一部分,研究了SNGA在5和10 L (NTP)1/min两种模式下的高速充电(最多2 min)和慢速放电(5和10 L)1/min)下的循环运行情况:主动控温模式和自然对流模式。针对SNGA循环运行的理论研究,建立了集总参数模型,并用实验数据进行了验证。调查结果得出了SNGA循环运行的特点,这些特点对于客运车辆的实际使用至关重要。
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来源期刊
CiteScore
1.90
自引率
18.20%
发文量
90
审稿时长
4-8 weeks
期刊介绍: Protection of Metals and Physical Chemistry of Surfaces is an international peer reviewed journal that publishes articles covering all aspects of the physical chemistry of materials and interfaces in various environments. The journal covers all related problems of modern physical chemistry and materials science, including: physicochemical processes at interfaces; adsorption phenomena; complexing from molecular and supramolecular structures at the interfaces to new substances, materials and coatings; nanoscale and nanostructured materials and coatings, composed and dispersed materials; physicochemical problems of corrosion, degradation and protection; investigation methods for surface and interface systems, processes, structures, materials and coatings. No principe restrictions exist related systems, types of processes, methods of control and study. The journal welcomes conceptual, theoretical, experimental, methodological, instrumental, environmental, and all other possible studies.
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