Development of Fe3O4–GO@Mn magnetic nanocatalyst for green synthesis of 1,2,3-triazole derivatives

IF 2.7 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Organometallic Chemistry Pub Date : 2026-01-15 Epub Date: 2025-11-17 DOI:10.1016/j.jorganchem.2025.123945

Mohammad Abushuhel , Hayjaa Mohaisen Mousa , G. PadmaPriya , Ahmad-Al Shaker , Subhashree Ray , Amrita Pal , Renu Sharma , Ashish Singh Chauhan , Kamran Hedayat

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Abstract

In the present research study, the Fe₃O₄–GO@Mn magnetic nanocatalyst was synthesized and successfully characterized by a range of techniques (XRD, FTIR, TEM, SEM, EDS, VSM, BET, and XPS) for a comprehensive characterization. This nanocomposite has good catalytic and magnetic characteristics because it has a Fe₃O₄ magnetic core, Mn layers, and is supported by graphene oxide; it is magnetic and allows for simple separation and multiple recycling. The reaction should be successful using this nanocatalyst for the synthesis of a variety of 1,2,3-triazole compounds with high efficiency and shorter reaction time, which was recommended under optimal conditions (temperature 80 °C, ethanol/water solvent, and time 40 min). Moreover, using a variety of substrates also showed the potential of the nanocatalyst to react with a diverse set of substrates, indicating good performance and versatility. The structural and functional stability of this nanocatalyst was confirmed, considering multiple recycling cycles, making it a choice for the industries and green chemistry.

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绿色合成1,2,3-三唑衍生物用Fe3O4 - GO@Mn磁性纳米催化剂的研制

本研究合成了Fe₃O₄- GO@Mn磁性纳米催化剂，并通过XRD、FTIR、TEM、SEM、EDS、VSM、BET、XPS等技术对其进行了全面表征。该纳米复合材料具有Fe₃O₄磁芯、Mn层，并由氧化石墨烯支撑，因此具有良好的催化和磁性；它是磁性的，允许简单的分离和多次回收。在最佳条件下（温度80℃，乙醇/水溶剂，反应时间40 min），该纳米催化剂可以高效、短时间合成多种1,2,3-三唑类化合物。此外，使用多种底物也显示了纳米催化剂与多种底物反应的潜力，表明了良好的性能和通用性。该纳米催化剂的结构和功能稳定性得到了证实，考虑到多次循环利用，使其成为工业和绿色化学的选择。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Organometallic Chemistry 化学-无机化学与核化学

CiteScore

4.40

自引率

8.70%

发文量

221

审稿时长

36 days

期刊介绍： The Journal of Organometallic Chemistry targets original papers dealing with theoretical aspects, structural chemistry, synthesis, physical and chemical properties (including reaction mechanisms), and practical applications of organometallic compounds. Organometallic compounds are defined as compounds that contain metal - carbon bonds. The term metal includes all alkali and alkaline earth metals, all transition metals and the lanthanides and actinides in the Periodic Table. Metalloids including the elements in Group 13 and the heavier members of the Groups 14 - 16 are also included. The term chemistry includes syntheses, characterizations and reaction chemistry of all such compounds. Research reports based on use of organometallic complexes in bioorganometallic chemistry, medicine, material sciences, homogeneous catalysis and energy conversion are also welcome. The scope of the journal has been enlarged to encompass important research on organometallic complexes in bioorganometallic chemistry and material sciences, and of heavier main group elements in organometallic chemistry. The journal also publishes review articles, short communications and notes.