Distinct Design for Two Terminal Crystalline Silicon Bottom-Based III–V Tandem Devices via Direct Electrode Interconnection and Enlarged Bottom Area

IF 5.5 3区 材料科学 Q2 CHEMISTRY, PHYSICAL
Muhammad Aleem Zahid, , , Seungyong Han, , , Syed Azkar UI Hasan, , , Vinh-Ai Dao, , , Minh Phuong Nguyen, , , Duy Phong Pham*, , and , Junsin Yi*, 
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Abstract

An innovative two-terminal III–V/c-Si multijunction device is constructed using direct electrode connections and extending the bottom area to improve carrier transport and current matching between the top III–V and bottom c-Si devices. A commercial triple junction GaInP2/InGaAs/Ge top cell (1 cm2) with a complete cover electrode at the rear is connected directly to a silicon heterojunction (SHJ) bottom device using silver paste. The area of the SHJ bottom device is enlarged from 0.69 cm2 to 15 cm2 to match the current density of the top. With a small active area of 0.69 cm2, the bottom device has a current density of 13.6 mA/cm2, comparable to the top device’s (13.5 mA/cm2). By optimizing the SHJ bottom, the multijunction device achieves an impressive efficiency of 39.5% with a short circuit current density of 13.5 mA/cm2, an open circuit voltage of 3.45 V, and an 85% fill factor. This initial design demonstrates the potential to significantly improve the efficiency of a two-terminal III–V/c-Si tandem device by increasing the matching current levels of both top and bottom cells.

Abstract Image

通过直接电极互连和扩大底部面积的两端晶体硅底部III-V串联器件的独特设计
采用电极直接连接和扩大底部面积的方法,构建了一种创新的双端III-V /c-Si多结器件,以改善顶部III-V和底部c-Si器件之间的载流子输运和电流匹配。一个商用三结GaInP2/InGaAs/Ge顶部电池(1 cm2),背面有一个完整的覆盖电极,使用银膏直接连接到硅异质结(SHJ)底部器件。SHJ底部装置的面积从0.69 cm2扩大到15 cm2,以匹配顶部的电流密度。底部器件的有源面积很小,为0.69 cm2,电流密度为13.6 mA/cm2,与顶部器件(13.5 mA/cm2)相当。通过优化SHJ底部,该多结器件在短路电流密度为13.5 mA/cm2,开路电压为3.45 V,填充系数为85%的情况下实现了39.5%的效率。该初步设计表明,通过增加顶部和底部电池的匹配电流水平,可以显著提高双端III-V /c-Si串联器件的效率。
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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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