Finely Tunable Thermal Expansion of NiTi by Stress-Induced Martensitic Transformation and Thermomechanical Training

Abstract

Tailoring the thermal expansion of martensitic materials by crystallographic texture and anisotropic variation of lattice parameters is a promising route to the flexible design of thermally stable systems. NiTi alloys are prototype materials in this respect, exhibiting shape-memory and superelastic properties owing to their thermoelastic martensitic transformations. Here, we propose a method to realize finely tunable coefficients of thermal expansion (CTE) for the NiTi alloy based on a special combination of mechanical and thermal training. We achieve a near-zero in-plane CTE smaller than that of the FeNi-based Invar alloy. Atomistic simulations and theoretical calculations guide the method design and clarify the underlying mechanisms of the relationship between the processing conditions, the microstructural evolution, and the thermal expansion behavior. The directions for further, finer adjustments of the CTE without constraints on the shape of the materials are indicated.