Metal-Organic Frameworks of Zinc with Tetrazine and Carboxylate Ligands

IF 1.4 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Structural Chemistry Pub Date : 2025-10-09 DOI:10.1134/S0022476625090203

D. S. Kolevatov, N. O. Druzhkov, I. A. Yakushev, P. V. Dorovatovskii, A. V. Piskunov

引用次数: 0

Abstract

The reaction of zinc nitrate with 3,6-di-4-pyridyl-1,2,4,5-tetrazine (4-DPT), 3,6-di-3-pyridyl-1,2,4,5-tetrazine (3-DPT), and trans-β-hydromuconic acid (H₂TBHMA) yields new MOFs of the following compositions: [Zn(3-DPT)(DMF)(NO₃)₂] (1), [Zn(3-DPT)(TBHMA)]·(MeOH) (2·MeOH), and [Zn₂(4-DPT)₂(TBHMA)(NO₃)₂]·2MeOH (3·2MeOH). Structures of the compounds are studied by single crystal X-ray diffraction (CIF file CCDC Nos. 2450436(1), 2450437 (2), 2450438 (3)).

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锌与四嗪和羧酸盐配体的金属有机骨架

硝酸锌与3,6-二-4-吡啶-1,2,4,5-四嗪（4- dpt）、3,6-二-3-吡啶-1,2,4,5-四嗪（3- dpt）和反式β-hydromuconic acid （H2TBHMA）反应生成新的mof: [Zn(3- dpt)(DMF)(NO3)2](1)、[Zn(3- dpt)(TBHMA)]·（MeOH）（2·MeOH）和[Zn2(4- dpt)2(TBHMA)(NO3)2]·2MeOH（3·2MeOH）。通过单晶x射线衍射研究了化合物的结构(CIF文件CCDC号2450436(1),2450437（2),2450438(3)）。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Structural Chemistry 化学-无机化学与核化学

CiteScore

1.60

自引率

12.50%

发文量

142

审稿时长

8.3 months

期刊介绍： Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.