{"title":"Di-chlorido-[2-(pyridin-2-yl-κ<i>N</i>)-1,5-naphthyridine-κ<i>N</i> <sup>1</sup>]zinc(II).","authors":"Kodai Tsubokawa, Takuro Iida, Kiyoshi Tsuge, Hideki Ohtsu","doi":"10.1107/S2414314625007643","DOIUrl":null,"url":null,"abstract":"<p><p>The title zinc(II) complex, [ZnCl<sub>2</sub>(C<sub>13</sub>H<sub>9</sub>N<sub>3</sub>)], crystallizes in the triclinic space group <i>P</i>1. The coordination environment around the zinc(II) ion in the title complex can be described as a distorted tetra-hedron formed by the two N atoms of the NAD<sup>+</sup>/NADH model ligand pn [pn = 2-(pyridin-2-yl)[1,5]naphthyridine] and two Cl<sup>-</sup> ions. There are <i>π</i>-<i>π</i> stacking inter-actions in the crystal packing of the title compound.</p>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 Pt 9","pages":"x250764"},"PeriodicalIF":0.0000,"publicationDate":"2025-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12498035/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1107/S2414314625007643","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/9/1 0:00:00","PubModel":"eCollection","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The title zinc(II) complex, [ZnCl2(C13H9N3)], crystallizes in the triclinic space group P1. The coordination environment around the zinc(II) ion in the title complex can be described as a distorted tetra-hedron formed by the two N atoms of the NAD+/NADH model ligand pn [pn = 2-(pyridin-2-yl)[1,5]naphthyridine] and two Cl- ions. There are π-π stacking inter-actions in the crystal packing of the title compound.