Synthesis of Ketoximes Derived from 5-(2-[(Benzoylamino)-3-methylphenyl]-5-oxopentanoic Acid and Its Methyl Ester and N-tosyl-2-(5-oxopentanoyl)-, N-tosyl-2-(6-oxohexanoyl)-, and N-pivaloyl-2-(5-oxohexanoyl)aniline Acetals

IF 0.9 4区化学 Q4 CHEMISTRY, ORGANIC

Russian Journal of Organic Chemistry Pub Date : 2025-10-08 DOI:10.1134/S1070428025601700

R. R. Safargalin, R. R. Gataullin

引用次数: 0

Abstract

Dimethyl acetals of N-tosyl-2-(5-oxopentanoyl)-, N-tosyl-2-(6-oxohexanoyl)-, and N-pivaloyl-2-(5-oxohexanoyl)anilines have been synthesized. The resulting acetals, as well as 5-(2-[(benzoylamino)-3-methylphenyl]-5-oxopentanoic acid and its methyl ester were reacted with hydroxylamine to obtain the corresponding ketoximes as syn/anti isomer mixtures.

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5-(2-[（苯甲酰氨基）-3-甲基苯基]-5-氧戊烯酸及其甲酯及n - toyl -2-（5-氧戊烯醇）-、n - toyl -2-（6-氧己醇）-和n - pivalyl -2-（5-氧己醇）苯胺缩醛衍生物酮肟的合成

合成了n - toyl -2-（5-氧戊烷基）-、n - toyl -2-（6-氧己烷基）-和n - pivalyl -2-（5-氧己烷基）苯胺的二甲基缩醛。所得缩醛、5-(2-[（苯甲酰氨基）-3-甲基苯基]-5-氧戊酸及其甲酯与羟胺反应得到相应的酮肟作为顺/抗异构体混合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Russian Journal of Organic Chemistry 化学-有机化学

CiteScore

1.40

自引率

25.00%

发文量

139

审稿时长

3-6 weeks

期刊介绍： Russian Journal of Organic Chemistry is an international peer reviewed journal that covers all aspects of modern organic chemistry including organic synthesis, theoretical organic chemistry, structure and mechanism, and the application of organometallic compounds in organic synthesis.