Probing Supramolecular Structures in Solution by Resonant Energy Transfer in the X-ray range

IF 7.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chemical Science Pub Date : 2025-10-06 DOI:10.1039/d5sc05911a

Viola Caroline C D'Mello, V. Rao Mundlapati, Jeremy DONON, Valerie Brenner, Michel Mons, Denis CEOLIN, Eric Gloaguen

引用次数: 0

Abstract

Supramolecular structures in solution are probed using Far-Zone Resonant Energy Transfer (FZRET) in an aqueous potassium acetate microjet. This advanced X-ray spectroscopic technique relies on the resonant energy transfer between donor atoms, i.e. core-ionised potassium ions, and acceptor atoms a few nm away. These experiments reveal an inhomogeneous distribution of ions in water, and are consistent with the presence of nm-sized ionic clusters at 4.1 M concentration.

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用x射线范围内共振能量转移探测溶液中的超分子结构

采用远区共振能量转移（FZRET）技术在醋酸钾微射流中探测溶液中的超分子结构。这种先进的x射线光谱技术依赖于供体原子（即核心电离的钾离子）与几纳米外的受体原子之间的共振能量转移。这些实验揭示了离子在水中的不均匀分布，并与4.1 M浓度下纳米级离子团的存在相一致。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical Science CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

14.40

自引率

4.80%

发文量

1352

审稿时长

2.1 months

期刊介绍： Chemical Science is a journal that encompasses various disciplines within the chemical sciences. Its scope includes publishing ground-breaking research with significant implications for its respective field, as well as appealing to a wider audience in related areas. To be considered for publication, articles must showcase innovative and original advances in their field of study and be presented in a manner that is understandable to scientists from diverse backgrounds. However, the journal generally does not publish highly specialized research.