Synthesis of Sulfondiimidoates by Desoxychlorination of Sulfonimidamides.

IF 5 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-10-02 DOI:10.1021/acs.orglett.5c03831

Erik Friedrich,Philip Freund,Christian Lorenz,Timo Heinrich,Dorian Didier,Michael Reggelin

引用次数: 0

Abstract

A synthetic procedure toward sulfondiimidoates, the aza-oxo inverse sulfonamides, was developed. The sulfondiimidoates reported here were synthesized by desoxychlorination of sulfonimidamides. The in situ generated sulfondiimidoyl chlorides were transformed into the desired sulfondiimidoates by alcoholysis. The method presented allows for redox-neutral access to sulfondiimidoates.

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磺胺酰亚胺脱氧氯化法合成磺酰二酰亚胺酯。

研究了偶氮氧反相磺胺类化合物磺酰二氨基甲酸酯的合成方法。本文报道的磺胺二酰亚胺酯是由磺胺二酰亚胺脱氧氯化合成的。原位生成的磺胺二酰氯经醇解转化为所需的磺胺二酰氯。所提出的方法允许氧化还原中性获得磺酰二氨基甲酸酯。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.