N. Braud , L. Buß , L. Merte , H. Wallander , J.-O. Krisponeit , T. Schmidt , E. Lundgren , J.I. Flege , J. Falta
{"title":"Growth and oxidation of ultra-thin Pt-Sn layers on Pt(111) by molecular and atomic oxygen","authors":"N. Braud , L. Buß , L. Merte , H. Wallander , J.-O. Krisponeit , T. Schmidt , E. Lundgren , J.I. Flege , J. Falta","doi":"10.1016/j.ultramic.2025.114243","DOIUrl":null,"url":null,"abstract":"<div><div>The preparation of ultra-thin PtSn-alloyed layers by molecular beam epitaxy was studied using low-energy electron microscopy (LEEM) and micro-diffraction (<span><math><mi>μ</mi></math></span>-LEED). Deposition at a sample temperature of 435 °C initially results in the formation of a Pt<span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span>Sn/Pt(111) layer showing a (2 × 2) reconstruction. With continued Sn deposition, a Pt<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>Sn/Pt(111) layer develops, showing a (<span><math><mrow><msqrt><mrow><mn>3</mn></mrow></msqrt><mo>×</mo><msqrt><mrow><mn>3</mn></mrow></msqrt></mrow></math></span>)R30° reconstruction. An ultra-thin tin oxide was formed from the (2 × 2) surface by exposure to molecular oxygen at temperatures of 500 °C and 590 °C, respectively. LEED shows the evolution of a new surface structure, which could be identified as an incommensurate rectangular <span><math><mfenced><mrow><mtable><mtr><mtd><mn>2</mn><mo>.</mo><mn>3</mn></mtd><mtd><mn>0</mn></mtd></mtr><mtr><mtd><mn>1</mn><mo>.</mo><mn>8</mn></mtd><mtd><mn>3</mn><mo>.</mo><mn>6</mn></mtd></mtr></mtable></mrow></mfenced></math></span> reconstruction with lattice parameters of a = (6.4 ± 0.1)<!--> <!-->Å <!--> <!-->and b = (8.6 ± 0.1)<!--> <!-->Å <!--> <!-->present in three domains rotated by 120° with respect to each other. This structure can be related to the zigzag reconstructions found for similar ultra-thin oxide systems. Contrarily, the (<span><math><mrow><msqrt><mrow><mn>3</mn></mrow></msqrt><mspace></mspace><mo>×</mo><mspace></mspace><msqrt><mrow><mn>3</mn></mrow></msqrt></mrow></math></span>)R30° structure showed no oxide formation even after extensive exposure to molecular oxygen. The usage of atomic oxygen, however, allows for oxidation of this surface and the growth of thicker oxides on both types of overlayers. At 500 °C this process is accompanied by substantial roughening of the surface.</div></div>","PeriodicalId":23439,"journal":{"name":"Ultramicroscopy","volume":"278 ","pages":"Article 114243"},"PeriodicalIF":2.0000,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ultramicroscopy","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S030439912500141X","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MICROSCOPY","Score":null,"Total":0}
引用次数: 0
Abstract
The preparation of ultra-thin PtSn-alloyed layers by molecular beam epitaxy was studied using low-energy electron microscopy (LEEM) and micro-diffraction (-LEED). Deposition at a sample temperature of 435 °C initially results in the formation of a PtSn/Pt(111) layer showing a (2 × 2) reconstruction. With continued Sn deposition, a PtSn/Pt(111) layer develops, showing a ()R30° reconstruction. An ultra-thin tin oxide was formed from the (2 × 2) surface by exposure to molecular oxygen at temperatures of 500 °C and 590 °C, respectively. LEED shows the evolution of a new surface structure, which could be identified as an incommensurate rectangular reconstruction with lattice parameters of a = (6.4 ± 0.1) Å and b = (8.6 ± 0.1) Å present in three domains rotated by 120° with respect to each other. This structure can be related to the zigzag reconstructions found for similar ultra-thin oxide systems. Contrarily, the ()R30° structure showed no oxide formation even after extensive exposure to molecular oxygen. The usage of atomic oxygen, however, allows for oxidation of this surface and the growth of thicker oxides on both types of overlayers. At 500 °C this process is accompanied by substantial roughening of the surface.
期刊介绍:
Ultramicroscopy is an established journal that provides a forum for the publication of original research papers, invited reviews and rapid communications. The scope of Ultramicroscopy is to describe advances in instrumentation, methods and theory related to all modes of microscopical imaging, diffraction and spectroscopy in the life and physical sciences.