Near-infrared luminescent Nd3+-doped zirconate transparent ceramics for efficient photothermal feedback window

IF 3.8 3区材料科学 Q1 MATERIALS SCIENCE, CERAMICS

Journal of the American Ceramic Society Pub Date : 2025-07-30 DOI:10.1111/jace.70151

Kailei Lu, Yuhong Xie, Wenhan Han, Mengqiu Guan, Zijie Li, Guixin Wang, Yucheng Ye, Jianqi Qi, Tiecheng Lu

{"title":"Near-infrared luminescent Nd3+-doped zirconate transparent ceramics for efficient photothermal feedback window","authors":"Kailei Lu, Yuhong Xie, Wenhan Han, Mengqiu Guan, Zijie Li, Guixin Wang, Yucheng Ye, Jianqi Qi, Tiecheng Lu","doi":"10.1111/jace.70151","DOIUrl":null,"url":null,"abstract":"Deploying a robust temperature feedback window is crucial for understanding thermally induced reactions in nuclear environments. However, existing photothermal windows suitable for radiation conditions largely function in the visible light range, which compromises the repeatability and uncertainty of temperature sensing. To address this, an efficient photothermal feedback window using near-infrared luminescent Nd3+ doped Y2Zr2O7 (YZO) highly transparent ceramics is developed. Studies on the effects of Nd3+ doping on the luminescence and lifetime of YZO:Nd ceramics revealed that the high-concentration luminescence quenching mechanism is re-absorption and dipole-quadrupole interaction. The developed YZO:Nd ceramic photothermal window exhibits acceptable sensitivity (0.108% K−1), high repeatability (>99.2%), and low temperature uncertainty (δTmin = 0.92 K). The paradigm demonstrated here provides a reference for creating high-performance photothermal windows for use in extreme radiation environments.","PeriodicalId":200,"journal":{"name":"Journal of the American Ceramic Society","volume":"108 12","pages":""},"PeriodicalIF":3.8000,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the American Ceramic Society","FirstCategoryId":"88","ListUrlMain":"https://ceramics.onlinelibrary.wiley.com/doi/10.1111/jace.70151","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}

引用次数: 0

Abstract

Deploying a robust temperature feedback window is crucial for understanding thermally induced reactions in nuclear environments. However, existing photothermal windows suitable for radiation conditions largely function in the visible light range, which compromises the repeatability and uncertainty of temperature sensing. To address this, an efficient photothermal feedback window using near-infrared luminescent Nd³⁺ doped Y₂Zr₂O₇ (YZO) highly transparent ceramics is developed. Studies on the effects of Nd³⁺ doping on the luminescence and lifetime of YZO:Nd ceramics revealed that the high-concentration luminescence quenching mechanism is re-absorption and dipole-quadrupole interaction. The developed YZO:Nd ceramic photothermal window exhibits acceptable sensitivity (0.108% K⁻¹), high repeatability (>99.2%), and low temperature uncertainty (δT_min = 0.92 K). The paradigm demonstrated here provides a reference for creating high-performance photothermal windows for use in extreme radiation environments.

Abstract Image

查看原文本刊更多论文

近红外发光掺Nd3+锆酸盐透明陶瓷的高效光热反馈窗口

部署一个强大的温度反馈窗口对于理解核环境中的热诱导反应至关重要。然而，现有的适用于辐射条件的光热窗主要在可见光范围内工作，这损害了温度传感的可重复性和不确定性。为了解决这一问题，利用近红外发光Nd3+掺杂Y2Zr2O7 （YZO）高透明陶瓷，开发了一种高效的光热反馈窗口。研究了Nd3+掺杂对YZO:Nd陶瓷发光和寿命的影响，发现其高浓度猝灭机制是重吸收和偶极子-四极子相互作用。YZO:Nd陶瓷光热窗具有可接受的灵敏度（0.108% K−1）、高重复性（>99.2%）和低温度不确定度（δTmin = 0.92 K）。这里演示的范例为创建用于极端辐射环境的高性能光热窗提供了参考。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of the American Ceramic Society 工程技术-材料科学：硅酸盐

CiteScore

7.50

自引率

7.70%

发文量

590

审稿时长

2.1 months

期刊介绍： The Journal of the American Ceramic Society contains records of original research that provide insight into or describe the science of ceramic and glass materials and composites based on ceramics and glasses. These papers include reports on discovery, characterization, and analysis of new inorganic, non-metallic materials; synthesis methods; phase relationships; processing approaches; microstructure-property relationships; and functionalities. Of great interest are works that support understanding founded on fundamental principles using experimental, theoretical, or computational methods or combinations of those approaches. All the published papers must be of enduring value and relevant to the science of ceramics and glasses or composites based on those materials. Papers on fundamental ceramic and glass science are welcome including those in the following areas: Enabling materials for grand challenges[...] Materials design, selection, synthesis and processing methods[...] Characterization of compositions, structures, defects, and properties along with new methods [...] Mechanisms, Theory, Modeling, and Simulation[...] JACerS accepts submissions of full-length Articles reporting original research, in-depth Feature Articles, Reviews of the state-of-the-art with compelling analysis, and Rapid Communications which are short papers with sufficient novelty or impact to justify swift publication.