Bingkun Huang, Bin Wang, Feifei Zhao, Yukai Xu, Haizeng Li, Jia-Yue Yang, William W. Yu
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引用次数: 0
Abstract
Conventional reversible manganese dioxide (MnO2) electrodeposition-based smart windows typically endure the constraints of narrow light modulation range, non-neutral color, and highly acidic electrolytes. Herein, novel Zn/MnO2 dual-electrodeposition-based smart windows are constructed utilizing near-neutral electrolytes (pH = 5.74). The devices broaden the light modulation range of MnO2 by reversible Zn electrodeposition, achieving a remarkable color change between transparent and neutral dark brown (chroma C* = 9.48). Furthermore, an iodide (I−) as a redox mediator is used to significantly prolong the devices’ cycling durability by promoting the dissolution of MnO2 and Zn. I− chemically reduces MnO2 to form Mn2+ and is oxidized to triiodide (I3−), I3− then spontaneously oxidizes Zn to form Zn2+ and is reduced back to I−, thus completing one mediator cycle. Consequently, the devices with the I− mediator exhibit impressive cycling durability (1,000 vs 60 cycles). Finally, the significant potential difference between the Zn and MnO2 electrodes endows the devices with excellent energy storage performance. The study offers a line of thought for developing novel multifunctional devices.
期刊介绍:
Advanced Optical Materials, part of the esteemed Advanced portfolio, is a unique materials science journal concentrating on all facets of light-matter interactions. For over a decade, it has been the preferred optical materials journal for significant discoveries in photonics, plasmonics, metamaterials, and more. The Advanced portfolio from Wiley is a collection of globally respected, high-impact journals that disseminate the best science from established and emerging researchers, aiding them in fulfilling their mission and amplifying the reach of their scientific discoveries.