Ruisi Gao, Feifan Yang, Liang Li, Ling Lin, Lin Zhu, Jinian Hao, Chuanhao Li, Shuo Chen, Guangzu Zhang, Kanghua Li
{"title":"Boosting Performance of ZnO/(Bi,Sb)2Se3 Short-Wavelength Infrared Photodetector via ZnTe Hole-Transport Layer","authors":"Ruisi Gao, Feifan Yang, Liang Li, Ling Lin, Lin Zhu, Jinian Hao, Chuanhao Li, Shuo Chen, Guangzu Zhang, Kanghua Li","doi":"10.1002/adom.202501610","DOIUrl":null,"url":null,"abstract":"<p>Infrared photodetectors based on (Bi,Sb)<sub>2</sub>Se<sub>3</sub> alloys have attracted considerable attention owing to their tunable bandgaps and high carrier mobility, making them promising candidates for broadband detection. However, their performance is hindered by high dark current density and inefficient carrier extraction. Herein, ZnTe is introduced as a hole-transport layer (HTL) to reconfigure the band structure and fabricate a high-performance ZnO/(Bi,Sb)<sub>2</sub>Se<sub>3</sub>/ZnTe photodetector. By systematically tuning the ZnTe HTL thickness, a 53% enhancement in EQE (16.2% at 1300 nm) and a 50% reduction in dark current density (97.4 µA cm<sup>−2</sup>, at −0.5 V) are achieved compared to HTL-free devices. SCAPS simulation elucidates that the designed (Bi,Sb)<sub>2</sub>Se<sub>3</sub>/ZnTe heterojunction effectively suppresses electron backflow while enhancing hole extraction, thereby boosting performance. Therefore, the optimized device exhibits a notably fast response time (12/107.5 ns rise/fall) and a wide linear dynamic range (LDR, 96 dB). Additionally, unencapsulated devices retain 97.7% of their initial performance after 322 h of operating at 90 °C and withstand extreme annealing at 150°C, surpassing many state-of-the-art detectors. This approach provides a scalable, low-cost, and eco-friendly strategy for developing high-performance, high-speed, and high-stability infrared photodetection systems.</p>","PeriodicalId":116,"journal":{"name":"Advanced Optical Materials","volume":"13 28","pages":""},"PeriodicalIF":7.2000,"publicationDate":"2025-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Optical Materials","FirstCategoryId":"88","ListUrlMain":"https://advanced.onlinelibrary.wiley.com/doi/10.1002/adom.202501610","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Infrared photodetectors based on (Bi,Sb)2Se3 alloys have attracted considerable attention owing to their tunable bandgaps and high carrier mobility, making them promising candidates for broadband detection. However, their performance is hindered by high dark current density and inefficient carrier extraction. Herein, ZnTe is introduced as a hole-transport layer (HTL) to reconfigure the band structure and fabricate a high-performance ZnO/(Bi,Sb)2Se3/ZnTe photodetector. By systematically tuning the ZnTe HTL thickness, a 53% enhancement in EQE (16.2% at 1300 nm) and a 50% reduction in dark current density (97.4 µA cm−2, at −0.5 V) are achieved compared to HTL-free devices. SCAPS simulation elucidates that the designed (Bi,Sb)2Se3/ZnTe heterojunction effectively suppresses electron backflow while enhancing hole extraction, thereby boosting performance. Therefore, the optimized device exhibits a notably fast response time (12/107.5 ns rise/fall) and a wide linear dynamic range (LDR, 96 dB). Additionally, unencapsulated devices retain 97.7% of their initial performance after 322 h of operating at 90 °C and withstand extreme annealing at 150°C, surpassing many state-of-the-art detectors. This approach provides a scalable, low-cost, and eco-friendly strategy for developing high-performance, high-speed, and high-stability infrared photodetection systems.
期刊介绍:
Advanced Optical Materials, part of the esteemed Advanced portfolio, is a unique materials science journal concentrating on all facets of light-matter interactions. For over a decade, it has been the preferred optical materials journal for significant discoveries in photonics, plasmonics, metamaterials, and more. The Advanced portfolio from Wiley is a collection of globally respected, high-impact journals that disseminate the best science from established and emerging researchers, aiding them in fulfilling their mission and amplifying the reach of their scientific discoveries.