{"title":"Mn(I)-Complex Catalyzed Upcycling of Polyethylene Terephthalate to α-Hydroxy Carboxylic Acids.","authors":"Soham Das Adhikary, Sayan K Jana, Biplab Maji","doi":"10.1002/anie.202513145","DOIUrl":null,"url":null,"abstract":"<p><p>The chemical upcycling of poly(ethylene terephthalate) (PET) waste into value-added products presents a promising strategy to address global plastic pollution. Here, we report a manganese-catalyzed, one-pot approach for tandem PET depolymerization and acceptorless dehydrogenative coupling (ADC) to selectively produce α-hydroxycarboxylic acids (α-HCAs), including glycolic, lactic, and higher-value derivatives, along with terephthalic acid (TPA) and H<sub>2</sub> gas. Employing bench-stable (PNP)Mn(I)-pincer complexes, this cascade process operates under mild conditions (120-140 °C) and accommodates a broad range of primary alcohol coupling partners, enabling the synthesis of valuable biodegradable polymer precursors (glycolic and lactic acid) and higher α-HCAs. Notably, the system exhibits exceptional tolerance to common plastic additives and requires no energy-intensive pretreatment, achieving near-quantitative TPA recovery and significant H<sub>2</sub> evolution. This work demonstrates how base-metal catalysis can bridge plastic waste remediation and sustainable chemical synthesis, offering a practical pathway toward circular polymer economies.</p>","PeriodicalId":520556,"journal":{"name":"Angewandte Chemie (International ed. in English)","volume":" ","pages":"e202513145"},"PeriodicalIF":16.9000,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie (International ed. in English)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/anie.202513145","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The chemical upcycling of poly(ethylene terephthalate) (PET) waste into value-added products presents a promising strategy to address global plastic pollution. Here, we report a manganese-catalyzed, one-pot approach for tandem PET depolymerization and acceptorless dehydrogenative coupling (ADC) to selectively produce α-hydroxycarboxylic acids (α-HCAs), including glycolic, lactic, and higher-value derivatives, along with terephthalic acid (TPA) and H2 gas. Employing bench-stable (PNP)Mn(I)-pincer complexes, this cascade process operates under mild conditions (120-140 °C) and accommodates a broad range of primary alcohol coupling partners, enabling the synthesis of valuable biodegradable polymer precursors (glycolic and lactic acid) and higher α-HCAs. Notably, the system exhibits exceptional tolerance to common plastic additives and requires no energy-intensive pretreatment, achieving near-quantitative TPA recovery and significant H2 evolution. This work demonstrates how base-metal catalysis can bridge plastic waste remediation and sustainable chemical synthesis, offering a practical pathway toward circular polymer economies.