Effects of Synthesis Conditions on the Physicochemical Properties and Hemolytic Activity of Beta Zeolites

IF 1.1 4区 工程技术 Q3 CHEMISTRY, ORGANIC
E. Yu. Brazovskaya, Yu. A. Alikina, A. Yu. Artamonov, O. V. Shamova, O. Yu. Golubeva
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Abstract

The study investigates the effects of synthesis conditions on the physicochemical properties and biological activity of Beta zeolites. Specifically, it addresses the effects of the tetraethylammonium hydroxide (TEAOH) content in the reaction mixture on the crystallinity, particle size and morphology, textural properties, acidity, and hemolytic activity of the zeolites synthesized. Reducing the TEAOH content by factors of 2, 4, and 6 compared to the reference composition was found to lower the zeolite crystallinity, increase the mean particle size (from 240 to 515 nm), change the particle morphology, and reduce the concentration of acid sites (from 822 to 638 µmol/g). Hemolytic activity tests demonstrated that the zeolite toxicity for human erythrocytes increased with a reduction in the TEAOH content.

Abstract Image

合成条件对β沸石理化性质及溶血活性的影响
研究了合成条件对β沸石的理化性质和生物活性的影响。具体来说,它解决了反应混合物中四乙基氢氧化铵(TEAOH)含量对合成的沸石的结晶度、粒度和形态、结构性质、酸度和溶血活性的影响。与参比组分相比,通过降低TEAOH含量的2、4和6,可以降低沸石的结晶度,增加平均粒径(从240 nm增加到515 nm),改变颗粒形态,降低酸位浓度(从822µmol/g减少到638µmol/g)。溶血活性试验表明,沸石对人红细胞的毒性随着TEAOH含量的降低而增加。
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来源期刊
Petroleum Chemistry
Petroleum Chemistry 工程技术-工程:化工
CiteScore
2.50
自引率
21.40%
发文量
102
审稿时长
6-12 weeks
期刊介绍: Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas. Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.
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