Isolation of Fulvic Acids by Extraction with n-Butanol

IF 0.9 4区 工程技术 Q4 CHEMISTRY, MULTIDISCIPLINARY
S. I. Zherebtsov, K. M. Shpakodraev, K. S. Votolin, N. V. Malyshenko
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引用次数: 0

Abstract

The article considers the methods of fulvic acid (FA) extraction from brown coals by the Tyurin–Forsyth method and by liquid-phase extraction with n-butyl alcohol. The data of technical and elemental analysis and IR and 13C NMR spectroscopy of the obtained fulvic acid samples and their fractions are presented. A comparative characterization of the obtained fulvic acids is carried out. It was established that the fulvic acid fractions obtained by the Tyurin–Forsyth method had a higher aromaticity index ( far = 32.79–61.54%) than the fulvic acids obtained by liquid-phase extraction with n-butyl alcohol ( far = 20.64%). Conclusions were made on the possibility and efficiency of using the liquid-phase extraction method with n-butyl alcohol for extracting brown coal fulvic acids.

Abstract Image

正丁醇萃取分离黄腐酸
研究了用Tyurin-Forsyth法和正丁醇液相萃取法从褐煤中提取黄腐酸的方法。给出了所得黄腐酸样品及其馏分的技术分析、元素分析和红外、13C核磁共振光谱数据。对所制得的黄腐酸进行了比较表征。结果表明,采用Tyurin-Forsyth萃取法得到的黄腐酸组分芳香指数(far = 32.79 ~ 61.54%)高于正丁醇液相萃取法得到的黄腐酸组分(far = 20.64%)。探讨了正丁醇液相萃取法提取褐煤黄腐酸的可行性和效率。
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来源期刊
Solid Fuel Chemistry
Solid Fuel Chemistry CHEMISTRY, MULTIDISCIPLINARY-ENERGY & FUELS
CiteScore
1.10
自引率
28.60%
发文量
52
审稿时长
6-12 weeks
期刊介绍: The journal publishes theoretical and applied articles on the chemistry and physics of solid fuels and carbonaceous materials. It addresses the composition, structure, and properties of solid fuels. The aim of the published articles is to demonstrate how novel discoveries, developments, and theories may be used in improved analysis and design of new types of fuels, chemicals, and by-products. The journal is particularly concerned with technological aspects of various chemical conversion processes and includes papers related to geochemistry, petrology and systematization of fossil fuels, their beneficiation and preparation for processing, the processes themselves, and the ultimate recovery of the liquid or gaseous end products.
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